{"id":78,"date":"2014-10-27T21:19:01","date_gmt":"2014-10-27T20:19:01","guid":{"rendered":"http:\/\/blog.uclm.es\/fernandocarrillo\/?page_id=78"},"modified":"2026-03-17T16:32:00","modified_gmt":"2026-03-17T16:32:00","slug":"mi-investigacion","status":"publish","type":"page","link":"https:\/\/blog.uclm.es\/fernandocarrillo\/mi-investigacion\/","title":{"rendered":"Mi investigaci\u00f3n"},"content":{"rendered":"

La investigaci\u00f3n desarrollada en nuestros laboratorios se lleva a cabo gracias a las ayudas de MICIU\/AEI\/10.13039\/501100011033 (Proyectos PID2020-117353GB-I00 y RED2022-134287-T), Junta de Comunidades de Castilla-La Mancha y la Uni\u00f3n Europea a trav\u00e9s del programa FEDER (Proyecto SBPLY\/23\/180225\/000021), y la Universidad de Castilla-La Mancha (Proyecto 2022-GRIN-34031).<\/p>\n

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\"Logotipo\"<\/p>\n

INVESTIGACI\u00d3N<\/strong><\/h1>\n

\"Guanidines:<\/p>\n

Mi investigaci\u00f3n se ha movido mucho a lo largo de las series de transici\u00f3n. Comenc\u00e9, durante mis Tesis de Grado y de Doctorado, a investigar la qu\u00edmica organomet\u00e1lica del niobio, en complejos metaloceno con ligandos hidruro. La reactividad de este tipo de compuestos frente a cationes de oro, plata o cobre, permiti\u00f3 obtener interesantes especies bimet\u00e1licas <\/a>que, adem\u00e1s de por su belleza, presentaban a dichos ligandos hidruro manifestando un comportamiento no convencional. Este tipo de complejos presentaban acoplamiento nuclear mediante intercambio cu\u00e1ntico de espines, que es algo que suena un poco a palabrer\u00eda cient\u00edfica, pero que ten\u00eda que ver con la formaci\u00f3n de mol\u00e9culas de hidr\u00f3geno, donde los \u00e1tomos de hidr\u00f3geno presentaban espectros de resonancia magn\u00e9tica nuclear, con un acoplamiento que solo era explicable si se produc\u00eda un giro, cuya barrera energ\u00e9tica se superaba a trav\u00e9s de un t\u00fanel cu\u00e1ntico.<\/p>\n

Adem\u00e1s, estudi\u00e9 el comportamiento de estos hidruros de niobio en procesos de activaci\u00f3n de enlaces Si-H<\/a>, como modelos de la activaci\u00f3n de enlaces C-H, y en procesos de inserci\u00f3n de estireno<\/a>, como aportaci\u00f3n al mecanismo de la polimerizaci\u00f3n catal\u00edtica de olefinas.<\/p>\n

Tras conseguir mi doctorado, viaj\u00e9 a Lyon, donde trabaj\u00e9 en un laboratorio dedicado a estudiar la utilidad de fijar complejos organomet\u00e1licos soportados sobre s\u00f3lidos, para conseguir catalizadores m\u00e1s eficaces y con aplicaci\u00f3n pr\u00e1ctica.<\/p>\n

En colaboraci\u00f3n con Elf-Atochem, estudiamos la s\u00edntesis y reactividad de complejos de circonio soportados sobre s\u00f3lidos \u00e1cidos, como la al\u00famina, para obtener catalizadores de polimerizaci\u00f3n de olefinas sin necesidad de cocatalizador<\/a>.<\/p>\n

A mi vuelta a Espa\u00f1a, retom\u00e9 la investigaci\u00f3n sobre la qu\u00edmica de hidruros de niobio<\/a>, siguiendo con la activaci\u00f3n de enlaces H-hetero\u00e1tomo, como H-Ge, H-Sn, <\/a>H-B<\/a> y otros. Al mismo tiempo, comenc\u00e9 a estudiar el uso de complejos monociclopentadienilo de circonio<\/a>, entre otros, como catalizadores de polimerizaci\u00f3n de olefinas.<\/p>\n

Aprovechando mis conocimientos sobre catalizadores moleculares soportados, empec\u00e9 a desarrollar una l\u00ednea de trabajo dedicada a fijar complejos con potencial catal\u00edtico sobre diferentes s\u00f3lidos soportes: \u00f3xidos de molibdeno o wolframio sobre zeolitas<\/a>, para reacciones de oxidaci\u00f3n; complejos de paladio, platino, rodio o iridio, sobre s\u00edlice<\/a>, para hidrogenaci\u00f3n de arom\u00e1ticos; complejos de circonio<\/a>, titanio,\u00a0hierro o vanadio<\/a>, para polimerizaci\u00f3n de olefinas. Este \u00faltimo punto me permiti\u00f3 tener una colaboraci\u00f3n muy intensa y fruct\u00edfera con REPSOL, para desarrollar catalizadores moleculares y soportados.<\/p>\n

Adem\u00e1s de conocer las interacciones complejo-soporte y sus implicaciones en la cat\u00e1lisis, hicimos un estudio exhaustivo del mecanismo de activaci\u00f3n de metalocenos <\/a>y no-metalocenos mediante derivados alumoxano y similares, utilizando las t\u00e9cnicas de espectroscopia ultravioleta-visible, infrarroja o la resonancia magn\u00e9tica nuclear.<\/p>\n

Tras esta experiencia con la industria, comenc\u00e9 la l\u00ednea que desarrollo en la actualidad. Durante el transcurso de la tesis que trataba sobre complejos de vanadio para polimerizaci\u00f3n de olefinas, surgi\u00f3 la idea de probar algunos de estos complejos como catalizadores en un proceso de s\u00edntesis org\u00e1nica muy atractivo. Se trata de una reacci\u00f3n muy simple que, mediante un proceso catal\u00edtico efectivo y de gran econom\u00eda at\u00f3mica, permite la adici\u00f3n de una amina a una carbodiimida<\/a>, para formar una guanidina. Las guanidinas son especies qu\u00edmicas presentes en multitud de sustancias naturales y sint\u00e9ticas con aplicaciones biol\u00f3gicas.\u00a0Al comprobar que este proceso catal\u00edtico necesitaba de un intermedio con ligandos b\u00e1sicos, nos propusimos Carlos Alonso<\/a>, profesor en la Facultad de Farmacia de la UCLM, y yo, que quiz\u00e1s alquilos met\u00e1licos simples, como los de cinc o magnesio, habituales en los laboratorios de Qu\u00edmica Inorg\u00e1nica y Org\u00e1nica<\/a>, pudieran realizar esta reacci\u00f3n con mejores prestaciones. De hecho, dietilcinc, uno de los primeros compuestos organomet\u00e1licos descritos<\/a>, es un catalizador muy eficaz para la reacci\u00f3n de guanilaci\u00f3n<\/a>.<\/p>\n

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Desde entonces, hemos preparado diferentes guanidinas, unas usadas como ligandos para preparar nuevos complejos de niobio<\/a>, circonio<\/a>, rutenio<\/a>\u00a0u osmio<\/a>,\u00a0pudiendo modificar esos ligandos casi al antojo, en funci\u00f3n de los reactivos que los forman y la disponibilidad en el cat\u00e1logo de Aldrich<\/a>. Esa variaci\u00f3n nos ha permitido estudiar su influencia en diferentes reacciones, tanto estequiom\u00e9tricas, como catal\u00edticas.<\/p>\n

En la actualidad, seguimos ampliando el uso de estos y otros catalizadores simples a otras reacciones de adici\u00f3n, para obtener nuevas mol\u00e9culas de inter\u00e9s. Igualmente, dise\u00f1amos nuevos derivados de amidinas con propiedades espec\u00edficas, que son usados como ligandos en la s\u00edntesis de complejos de metales especialmente reactivos, como zinc, magnesio, calcio o aluminio, o no metales, como boro. Algunos de estos complejos se muestran como muy eficientes en procesos catal\u00edticos de hidroboraci\u00f3n de CO2 y otras mol\u00e9culas como aldeh\u00eddos, cetonas o nitrilos, en la cicloadici\u00f3n de mol\u00e9culas insaturadas, o presentan propiedades luminiscentes. Otros han permitido la obtenci\u00f3n de carbonatos org\u00e1nicos c\u00edclicos usando CO2 como materia prima, un trabajo realizado en colaboraci\u00f3n con los Dres. Ren\u00e9 Rojas<\/a>, de la Pontificia Universidad Cat\u00f3lica de Chile, y la Dra. Mar\u00eda Luisa Valenzuela<\/a>, de la Universidad Aut\u00f3noma de Chile.<\/p>\n

Desde hace unos a\u00f1os, trabajamos en colaboraci\u00f3n con el Dr. Carlos Alonso<\/a>, de nuestra Facultad de Farmacia de Albacete en el desarrollo de nuevas mol\u00e9culas con potencial antitumoral, basadas en guanidinas.<\/p>\n

Finalmente, en los \u00faltimos a\u00f1os, nuestro grupo desarrolla, bajo la supervisi\u00f3n del Dr. David Elorriaga<\/a>, nuevas investigaciones sobre la obtenci\u00f3n de derivados org\u00e1nicos mediante el uso de compuestos organomet\u00e1licos polares en condiciones aer\u00f3bicas y con disolventes sostenibles.<\/p>\n

En muchos de estos trabajos, colaboramos con el Dr. Daniel Garc\u00eda-Viv\u00f3<\/a>, de la Universidad de Oviedo, en el estudio DFT de mecanismos de reacci\u00f3n.<\/p>\n

(Ver Publicaciones Recientes)<\/a><\/p>\n

English summary:<\/p>\n

Currently, we design new amidine derivatives with specific properties<\/strong>, which are used as ligands<\/strong> in the synthesis of especially reactive elements of the Main Group <\/strong>or as organocatalyts<\/strong>. Some of these complexes are very efficient in catalytic processes for small molecule<\/strong>s activation, in reactions as hydroboration or the synthesis of heterocycles. Others have allowed the synthesis of cyclic organic carbonates using CO2 as raw material.<\/p>\n

For some years now, we have been working on the development of new molecules with anti-tumour behaviour<\/strong>, based on guanidines.<\/p>\n

Finally, in recent years, we are developing new research on obtaining organic derivatives by using polar organometallic compounds under aerobic conditions and with sustainable solvents.<\/strong><\/p>\n

(See Recent Publications)<\/a><\/p>\n

ORCID ID<\/a><\/h1>\n

GOOGLE SCHOLAR<\/a><\/h1>\n
Publicaciones<\/strong><\/h5>\n
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  1. Carlos Gin\u00e9s, Blanca Parra-Cadenas, David Elorriaga, Daniel Garc\u00eda-Viv\u00f3, Rafael Fern\u00e1ndez-Gal\u00e1n, Alberto Ramos and Fernando Carrillo-Hermosilla: Efficient synthesis of cyclic carbonates and oxazolidinones by simple zinc guanidinato complexes.<\/em> Dalton Trans. 2026, 55, 4525\u20134534. DOI: 10.1039\/d6dt00139d<\/li>\n
  2. Carlos Gin\u00e9s, Blanca Parra-Cadenas, Rafael Fern\u00e1ndez-Gal\u00e1n, David Elorriaga, Alberto Ramos, Daniel Garc\u00eda-Viv\u00f3, Fernando Carrillo-Hermosilla: Exploring Ligand Effects in the Selective Catalytic Dehydrogenative Borylation of Alkynes with Aluminum.<\/em>\u00a0Adv. Synth. Catal. 2026, 368, e70177. https:\/\/doi.org\/10.1002\/adsc.70177<\/li>\n
  3. Carlos Gin\u00e9s, Blanca Parra-Cadenas, Fernando Carrillo-Hermosilla, David Elorriaga: Innovative Syntheses and Reactivity of Propiolamidines<\/em>. Molecules 2025, 30(3), 708. https:\/\/doi.org\/10.3390\/molecules30030708<\/li>\n
  4. Carlos Gin\u00e9s, Blanca Parra-Cadenas, Rafael Fern\u00e1ndez-Gal\u00e1n, Daniel Garc\u00eda-Viv\u00f3, David Elorriaga, Alberto Ramos, Fernando Carrillo-Hermosilla: Magnesium and Calcium Bisguanidinates: Catalytic Activity in the Hydroboration of Unsaturated Molecules. <\/em>Adv. Synth. Catal. 2025, 367, e202400843. https:\/\/doi.org\/10.1002\/adsc.202400843<\/li>\n
  5. Noelia Morata-Moreno, Ram\u00f3n P\u00e9rez-Tanoira, Almudena del Campo-Balguerias, Fernando Carrillo-Hermosilla, Marcos Hernando-Gozalo, Carlos Rescalvo-Casas, Ana V. Ocana, Pedro Segui, Carlos Alonso-Moreno, Francisco C. P\u00e9rez-Mart\u00ednez,\u00a0 and Milagros Molina-Alarc\u00f3n. A New Guanidine-Core Small-Molecule Compound as a Potential Antimicrobial Agent against Resistant Bacterial Strains.<\/em> Antibiotics 2024, 13(7), 609; https:\/\/doi.org\/10.3390\/antibiotics13070609.<\/li>\n
  6. Parra-Cadenas, Blanca; Bravo, Iv\u00e1n; Ripoll, Consuelo; Gin\u00e9s, Carlos; Elorriaga, David; Carrillo-Hermosilla, Fernando. Boron complexes with propiolamidinato ligands: synthesis, structure and photophysical properties. <\/em>Inorg. Chem., 2024, 63, 26, 12120\u201312132. https:\/\/doi.org\/10.1021\/acs.inorgchem.4c01241<\/li>\n
  7. Blanca Parra-Cadenas, Carlos Gin\u00e9s, Daniel Garc\u00eda-Viv\u00f3, David Elorriaga\u00a0 and Fernando Carrillo-Hermosilla. Zinc amidinate-catalysed cyclization reaction of carbodiimides and alkynes. An insight into the mechanism<\/em>. Dalton Transactions, 2024, 53, 10050 – 10054. DOI: 10.1039\/D4DT01265H. HOT ARTICLE<\/strong><\/li>\n
  8. Blanca Parra-Cadenas,\u00a0 Israel Fern\u00e1ndez, Fernando Carrillo-Hermosilla,\u00a0 Joaqu\u00edn Garc\u00eda-\u00c1lvarez and David Elorriaga. Addition of allyl Grignard to nitriles in air and at room temperature: experimental and computational mechanistic insights in pH-switchable synthesis. <\/em>Chem. Sci., 2024,15, 5929-5937. DOI: 10.1039\/D3SC06403D.<\/li>\n
  9. \u00c1ngela Mes\u00edas-Salazar, Ren\u00e9 S. Rojas, Fernando Carrillo-Hermosilla, Javier Mart\u00ednez, Antonio Anti\u00f1olo, Oleksandra S. Trofymchuk, Fabiane M. Nachtigall, Leonardo S. Santos and Constantin G. Daniliuc. Guanidinium iodide salts as single component catalysts for CO2 to epoxide fixation.<\/em> New J. Chem., 2024, 48, 105\u2013111.<\/span>DOI: 10.1039\/d3nj03959e<\/li>\n
  10. David Elorriaga, Blanca Parra-Cadenas, Paula P\u00e9rez-Ramos, Raquel G. Soengas, Fernando Carrillo-Hermosilla and Humberto Rodr\u00edguez-Solla. Imidazol(in)ium-2-Thiocarboxylate Zwitterion Ligands: Structural Aspects in Coordination Complexes. <\/em>Crystals 2023, 13(9), 1304\u20131321. <\/span>DOI: 10.3390\/cryst13091304<\/span><\/li>\n
  11. \n
    Almudena del Campo-Balguer\u00edas, Blanca Parra-Cadenas, Cristina Nieto-Jimenez, Iv\u00e1n Bravo, Consuelo Ripoll, Elisa Poyatos-Racionero, Pawel Gancarski, Fernando Carrillo-Hermosilla, Carlos Alonso-Moreno\u00a0 and Alberto Oca\u00f1a.<\/span> Guanylation Reactions for the Rational Design of Cancer Therapeutic Agents. <\/em>Int. J. Mol. Sci. 2023, 24(18), 13820\u2013<\/span>13835. DOI: 10.3390\/ijms24181382<\/div>\n<\/li>\n
  12. Alberto Ramos, Fernando Carrillo-Hermosilla, Rafael Fern\u00e1ndez-Gal\u00e1n, David Elorriaga, Jes\u00fas Naranjo, Antonio Anti\u00f1olo, and Daniel Garc\u00eda-Viv\u00f3. ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides. <\/em>Organometallics, 2022<\/span>, 41<\/span>, 21<\/span>, 2949\u20132957.<\/span>
    \nDOI: 10.1021\/acs.organomet.2c00372<\/li>\n
  13. Fernando Carrillo-Hermosilla, Rafael Fern\u00e1ndez-Gal\u00e1n, Alberto Ramos and David Elorriaga. Guanidinates as Alternative Ligands for Organometallic Complexes. <\/em>Molecules 2022<\/span>, <\/em>27, 5962-5993<\/span>. <\/em>DOI: 10.3390\/molecules27185962<\/li>\n
  14. \n
    David Elorriaga, <\/span><\/span>Fernando Carrillo-Hermosilla, <\/span><\/span>Blanca Parra-Cadenas, <\/span><\/span>Antonio Anti\u00f1olo, <\/span><\/span>Joaquin Garc\u00eda-\u00c1lvarez. Aerobic\/Room-Temperature-Compatible s-Block Organometallic Chemistry in Neat Conditions: A Missing Synthetic Tool for the Selective Conversion of Nitriles into Asymmetric Alcohols<\/em>. ChemSusChem 2022, 15, e202201348. DOI: 10.1002\/cssc.202201348<\/span><\/div>\n<\/li>\n
  15. \n
    Mar\u00eda Luisa Valenzuela, Desmond MacLeod-Carey, Cristian Soto Marfull, Jos\u00e9 Le\u00f3n-Baeza, Javier Mart\u00ednez, Antonio Anti\u00f1olo, Fernando Carrillo. Synthesis and Theoretical Study of New Guanylated Cyclophosphazenes and Their Use in the CO2 Fixation into Styrene Carbonate.\u00a0<\/em>J. Inorg. Organomet. Polym. 2022, 32, 1724\u20131735. DOI: <\/span>10.1007\/s10904-022-02264-6.<\/div>\n<\/li>\n
  16. \n
    David Elorriaga,\u00a0 Blanca Parra-Cadenas,\u00a0 Antonio Anti\u00f1olo,\u00a0 Fernando Carrillo-Hermosilla\u00a0 and Joaqu\u00edn Garc\u00eda-\u00c1lvarez. Combination of air\/moisture\/ambient temperature compatible organolithium chemistry with sustainable solvents: selective and efficient synthesis of guanidines and amidines.<\/em> Green Chem., 2022, 24, 800-812. DOI: 10.1039\/D1GC03393J<\/div>\n<\/li>\n
  17. \n
    Pedro J. Pacheco-Li\u00f1\u00e1n, Carlos Alonso-Moreno, Fernando Carrillo-Hermosilla, Andr\u00e9s Garz\u00f3n-Ruiz, Cristina Mart\u00edn, Carla S\u00e1ez, Jos\u00e9 Albaladejo, and Iv\u00e1n Bravo. Novel Fluorescence Guanidine Molecules for Selective Sulfate Anion Detection in Water Complex Samples over a Wide pH Range.<\/em> ACS Sens.<\/span>\u00a02021<\/span>, 6<\/span>,<\/span> 3224\u20133233. DOI: 10.1021\/acssensors.1c00876<\/span><\/div>\n<\/li>\n
  18. \n
    Yersica Rios Yepes, \u00c1ngela Mes\u00edas-Salazar, Alexandra Becerra, Constantin G. Daniliuc, Alberto Ramos, Rafael Fern\u00e1ndez-Gal\u00e1n, Antonio Rodr\u00edguez-Di\u00e9guez, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, and Ren\u00e9 S. Rojas. Mono- and Dinuclear Asymmetric Aluminum Guanidinates for the Catalytic CO2 Fixation into Cyclic Carbonates<\/em>. Organometallics 2021, 40, 16, 2859\u20132869. DOI: 10.1021\/acs.organomet.1c00319<\/div>\n<\/li>\n
  19. \n
    Ren\u00e9 S. <\/span>Rojas, <\/span><\/span>Karina <\/span>Mu\u00f1oz-Becerra, <\/span><\/span>Alejandro <\/span>Toro-Labb\u00e9, <\/span><\/span>Angela <\/span>Mes\u00edas-Salazar, <\/span><\/span>Iv\u00e1n <\/span>Mart\u00ednez, <\/span><\/span>Antonio <\/span>Anti\u00f1olo, <\/span><\/span>Fernando <\/span>Carrillo-Hermosilla, <\/span><\/span>Rafael <\/span>Fern\u00e1ndez-Gal\u00e1n, <\/span><\/span>Alberto <\/span>Ramos, <\/span><\/span>Constantin G. <\/span>Daniliuc.\u00a0 New guanidine-borane adducts: An experimental and theoretical approach<\/em>. Inorg. Chim. Acta 2021, 518, 120217-120224. DOI: 10.1016\/j.ica.2020.120217<\/span><\/span><\/span><\/div>\n<\/li>\n
  20. \n
    E. Huergo, R. Fern\u00e1ndez-Gal\u00e1n, A. Ramos, A. Anti\u00f1olo, F. Carrillo-Hermosilla, A. Rodr\u00edguez-Di\u00e9guez, D. Garc\u00eda-Viv\u00f3. Reactivity of\u00a0N-Phosphinoguanidines of the Formula (HNR)(Ph2<\/sub>PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from\u00a0N-Phosphinoguanidinates to Phosphinimine-Amidinates<\/em>.\u00a0Inorg. Chem.\u00a0<\/em>2020,\u00a059, 15262-15275. DOI:\u00a010.1021\/acs.inorgchem.0c02224<\/div>\n<\/li>\n
  21. \n
    Alberto Ramos, <\/span>Antonio Anti\u00f1olo, <\/span>Fernando<\/span>\u00a0Carrillo<\/span>–Hermosilla, <\/span><\/span>Rafael Fern\u00e1ndez-Gal\u00e1n. Ph2PCH2CH2B(C8H14) and Its Formaldehyde Adduct as Catalysts for the Reduction of CO2 with Hydroboranes.<\/em>\u00a0Inorg. Chem.<\/i><\/span>\u00a02020<\/span>, 59<\/span>, 14<\/span>, 9998\u201310012. DOI: 10.1021\/acs.inorgchem.0c01152<\/span><\/span><\/div>\n<\/li>\n
  22. \n
    \u00c1ngela Mes\u00edas-Salazar, Oleksandra S. Trofymchuk, Constantin G. Daniliuc, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Fabiane M. Nachtigall, Leonardo S. Santos, Ren\u00e9 S. Rojas. Copper (II) as catalyst for intramolecular cyclization and oxidation of (1,4-phenylene)bisguanidines to benzodiimidazole-diylidenes.<\/em> J. Catal. 2020, 382, 150-154 DOI: 10.1016\/j.jcat.2019.12.002<\/div>\n<\/li>\n
  23. \n
    \u00c1ngela Mes\u00edas-Salazar, Javier Mart\u00ednez, Ren\u00e9 S. Rojas, Fernando Carrillo-Hermosilla, Alberto Ramos, Rafael Fern\u00e1ndez-Gal\u00e1n and Antonio Anti\u00f1olo. Aromatic guanidines as highly active binary catalytic systems for the fixation of CO2 into cyclic carbonates under mild conditions.<\/em> Catal. Sci. Technol., 2019, 9, 3879-3886. DOI: 10.1039\/C9CY00667B<\/div>\n<\/li>\n
  24. \n
    A. Anti\u00f1olo, S. Garc\u00eda-Yuste, I. L\u00f3pez-Solera, A. Otero, M. T. Tercero-Morales, F. Carrillo-Hermosilla.\u00a0Reactivity studies on a trihydride niobocene complex towards \u03b1,\u03b2-Unsaturated carboxylic acids. J. Organomet. Chem<\/em>., 2019,\u00a0897, 120-129. DOI:\u00a010.1016\/j.jorganchem.2019.06.006<\/div>\n<\/li>\n
  25. \n
    Alberto Ramos, Antonio Anti\u00f1olo,\u00a0 Fernando Carrillo-Hermosilla,\u00a0 Rafael Fern\u00e1ndez-Gal\u00e1n\u00a0 and Daniel Garc\u00eda-Viv\u00f3:\u00a09-Borabicyclo[3.3.1]nonane: a metal-free catalyst\u00a0for the hydroboration of carbodiimides.\u00a0<\/em>Chem. Commun., 2019, 55, 3073. DOI:\u00a010.1039\/c9cc00593e<\/div>\n<\/li>\n
  26. \n
    Rafael Fern\u00e1ndez-Gal\u00e1n,\u00a0 Alberto Ramos,\u00a0 Estefan\u00eda Huergo, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Antonio Rodr\u00edguez-Di\u00e9guez and Daniel Garc\u00eda-Viv\u00f3:\u00a0Unusual ligand rearrangement: from N-phosphinoguanidinato to <\/em>phosphinimine-amidinato compounds.\u00a0<\/em>Chem. Commun., 2019, 55, 2809. DOI: 10.1039\/c9cc00432g<\/div>\n<\/li>\n
  27. \n
    Sonia Moreno, Alberto Ramos, Fernando Carrillo -Hermosilla, Antonio Rodr\u00edguez-Die\u0301guez,\u00a0Daniel Garc\u00eda-Vivo\u0301, Rafael Ferna\u0301ndez-Gala\u0301n, and Antonio Antin\u0303olo: Selective Three-Component Coupling for CO2 Chemical Fixation to\u00a0Boron Guanidinato Compounds.\u00a0<\/em>Inorg. Chem., 2018<\/span>,\u00a057<\/span>\u00a0(14), 8404\u20138413\u00a0DOI: 10.1021\/acs.inorgchem.8b01068<\/div>\n<\/li>\n
  28. \n
    Alberto Ramos, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Rafael Fern\u00e1ndez-Gal\u00e1n, Antonio Rodr\u00edguez-Di\u00e9guez and Daniel Garc\u00eda-Viv\u00f3: Carbodiimides as catalysts for the reduction of CO2 with boranes<\/em>. Chem. Commun., 2018, 54, 4700-4703. DOI: 10.1039\/C8CC02139B<\/div>\n<\/li>\n
  29. \n
    Pedro J. Pacheco-Li\u00f1\u00e1n, Jes\u00fas Fern\u00e1ndez-Sainz, Iv\u00e1n Bravo, Andr\u00e9s Garz\u00f3n-Ruiz, Carlos Alonso-Moreno, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo and Jos\u00e9 Albaladejo: Guanidine Substitutions in Naphthyl Systems to Allow a Controlled Excited-State Intermolecular Proton Transfer: Tuning Photophysical Properties in Aqueous Solution<\/em>. J. Phys. Chem. C, 2018, 122 (17), pp 9363\u20139373. DOI: 10.1021\/acs.jpcc.8b0257<\/div>\n<\/li>\n
  30. \n
    Antonio Mart\u00ednez, Sonia Moreno-Bl\u00e1zquez, Antonio Rodr\u00edguez-Di\u00e9guez, Alberto Ramos, Rafael Fern\u00e1ndez-Gal\u00e1n, Antonio Anti\u00f1olo and Fernando Carrillo-Hermosilla:\u00a0\u00a0Simple ZnEt2<\/sub><\/small>\u00a0as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies\u00a0<\/em>Dalton Trans., 2017, 46, 12923-12934.. DOI:\u00a010.1039\/C7DT02700A<\/div>\n<\/li>\n
  31. \n
    Alberto Ramos, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Rafael Fern\u00e1ndez-Gal\u00e1n, Mar\u00eda del Pilar Montero-Rama, Elena Villase\u00f1or, Antonio Rodr\u00edguez-Di\u00e9guez and Daniel Garc\u00eda-Viv\u00f3:\u00a0Insertion reactions of small unsaturated molecules in the N\u2013B bonds of boron guanidinates<\/em>\u00a0Dalton Trans., 2017,46, 10281-10299
    \nDOI:\u00a010.1039\/C7DT02081C<\/div>\n<\/li>\n
  32. \n
    Inmaculada Posadas, Carlos Alonso-Moreno, Iv\u00e1n Bravo, Fernando Carrillo-Hermosilla, Andr\u00e9s Garz\u00f3n, Noem\u00ed Villaseca, Isabel L\u00f3pez-Solera, Jos\u00e9 Albaladejo, Valent\u00edn Ce\u00f1a:\u00a0Synthesis, characterization, DNA interactions and antiproliferative\u00a0<\/em>activity on glioblastoma of iminopyridine platinum(II)\u00a0<\/em>chelate complexes <\/em>J. Inorg. Biochem., 2017, 168, 46-54.<\/div>\n<\/li>\n
  33. \n
    Marco De Tullio, Alberto Hern\u00e1n-G\u00f3mez, Zoe Livingstone, William Clegg, Alan R. Kennedy, Ross W. Harrington, Antonio Anti\u00f1olo, Antonio Mart\u00ednez, Fernando Carrillo-Hermosilla, Eva Hevia:\u00a0Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines<\/em> Chem. Eur. J., 2016, 22, 17646-17656. DOI:\u00a010.1002\/chem.201602906<\/div>\n<\/li>\n
  34. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Rafael Fern\u00e1ndez-Gal\u00e1n, Mar\u00eda Pilar Montero-Rama,Alberto Ramos, Elena Villase\u00f1or,Rene S. Rojas and\u00a0Antonio Rodr\u00edguez-Di\u00e9guez:\u00a0Dialkylboron guanidinates: syntheses, structures <\/em>and carbodiimide de-insertion reactions<\/em> Dalton Trans., 2016, 45, 15350.\u00a0DOI: 10.1039\/c6dt02913b<\/div>\n<\/li>\n
  35. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Rafael Fernandez-Galan, Jaime Martinez-Ferrer, Carlos Alonso-Moreno, Iv\u00e1n Bravo, Sonia Moreno-Bl\u00e1zquez, Manuel Salgado, Elena Villase\u00f1or, Jos\u00e9 Albaladejo: Tris(pentafluorophenyl)borane as an efficient catalyst in the guanylation reaction of amines. <\/em>Dalton Transactions 2016, 45, 10717. DOI:\u00a010.1039\/C6DT01237J<\/div>\n<\/li>\n
  36. \n
    Javier Francos, Pedro J. Gonz\u00e1lez-Liste, Luc\u00eda Men\u00e9ndez-Rodr\u00edguez, Pascale Crochet, Victorio Cadierno, Javier Borge, Antonio Anti\u00f1olo, Rafael Fern\u00e1ndez-Gal\u00e1n, Fernando Carrillo-Hermosilla: Half-Sandwich Guanidinate-Osmium(II) Complexes: Synthesis and Application in the Selective Dehydration of Aldoximes<\/em>. European Journal of Inorganic Chemistry 01\/2016; 393-402. DOI:10.1002\/ejic.201501221<\/div>\n<\/li>\n
  37. \n
    Iv\u00e1n Bravo, Carlos Alonso-Moreno, Inmaculada Posadas, Jos\u00e9 Albaladejo, Fernando Carrillo-Hermosilla, Valent\u00edn Ce\u00f1a, Andres Garzon, Isabel L\u00f3pez-Solera, Laura Romero-Castillo: Phenyl-Guanidine Derivatives as Potential Therapeutic Agents for Glioblastoma Multiforme: Catalytic Syntheses, Cytotoxic Effects and DNA Affinity<\/em>. RSC Advances 01\/2016; 6(10). DOI:10.1039\/C5RA17920C<\/div>\n<\/li>\n
  38. \n
    Daniel Nieto, Sonia Bru\u00f1a, Ana Ma Gonzalez-Vadillo, Josefina Perles, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Jos\u00e9 M. Padr\u00f3n, Gabriela B. Plata, Isabel Cuadrado: Catalytically Generated Ferrocene-Containing Guanidines as Efficient Precursors for New Redox-Active Heterometallic Platinum(II) Complexes with Anticancer Activity<\/em>. Organometallics 11\/2015; 34(22). DOI:10.1021\/acs.organomet.5b00751<\/div>\n<\/li>\n
  39. \n
    Luc\u00eda Men\u00e9ndez-Rodr\u00edguez, Eder Tom\u00e1s-Mendivil, Javier Francos, Pascale Crochet, Victorio Cadierno, Antonio Anti\u00f1olo, Rafael Fern\u00e1ndez-Gal\u00e1n, Fernando Carrillo-Hermosilla: Reactivity of the Dimer [{RuCl(\u03bc-Cl)(\u03b73:\u03b73-C10H16)}2] (C10H16 = 2,7-Dimethylocta-2,6-diene-1,8-diyl) toward Guanidines: Access to Ruthenium(IV) and Ruthenium(II) Guanidinate Complexes<\/em>. Organometallics 06\/2015; 34(12):2796-2809. DOI:10.1021\/acs.organomet.5b00070<\/div>\n<\/li>\n
  40. \n
    Iv\u00e1n Bravo, Carlos Alonso\u2010Moreno, Fernando Carrillo\u2010Hermosilla, Isabel L\u00f3pez\u2010Solera, Antonio Anti\u00f1olo, Jos\u00e9 Albaladejo: Toward the Prediction of Activity in the Ethylene Polymerisation of ansa-Bis(indenyl) Zirconocenes: Effect of the Stereochemistry and Hydrogenation of the Indenyl Moiety<\/em>. ChemPlusChem 03\/2015; DOI:10.1002\/cplu.201500008<\/div>\n<\/li>\n
  41. \n
    David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Isabel L\u00f3pez-Solera, Rafael Fern\u00e1ndez-Gal\u00e1n, Elena Villase\u00f1or: Mixed amido-\/imido-\/guanidinato niobium complexes: Synthesis and the effect of ligands on insertion reactions<\/em>. Dalton Transactions 09\/2014; 43(46). DOI:10.1039\/c4dt01975j<\/div>\n<\/li>\n
  42. \n
    Alan R. Cabrera, Elena Villase\u00f1or, Francisca Werlinger, Rene S. Rojas, Mauricio Valderrama, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Rafael F\u00e9rnadez-Galan: Grafting of the zirconium complexes [Zr(\u03b75-C5H5){NC-amidine}Cl2] and [Zr(\u03b75-C5H5)(NC-NacNac)Cl2] and the study of their behavior in ethylene polymerization<\/em>. Journal of Molecular Catalysis A Chemical 09\/2014; 391(1). DOI:10.1016\/j.molcata.2014.04.017<\/div>\n<\/li>\n
  43. \n
    Carlos Alonso-Moreno, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Antonio Otero: ChemInform Abstract: Guanidines: From Classical Approaches to Efficient Catalytic Syntheses<\/em>. Chemical Society Reviews 03\/2014; 43(10). DOI:10.1039\/c4cs00013g<\/div>\n<\/li>\n
  44. \n
    Rafael Fernandez-Galan, Juan-Antonio Navarro, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Isabel L\u00f3pez-Solera Elena Villase\u00f1or: Preparation and Structural Studies of Non-Symmetric Guanidinate-Supported Zirconium Complexes<\/em>. Australian Journal of Chemistry 01\/2014; 67(7):1063-1070. DOI:10.1071\/CH14181<\/div>\n<\/li>\n
  45. \n
    David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Isabel L\u00f3pez-Solera, Rafael Fern\u00e1ndez-Gal\u00e1n, Elena Villase\u00f1or: Unexpected mild C\u2013N bond cleavage mediated by guanidine coordination to a niobium iminocarbamoyl complex<\/em>. Chemical Communications 08\/2013; 49(77). DOI:10.1039\/c3cc44952a<\/div>\n<\/li>\n
  46. \n
    David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Isabel L\u00f3pez-Solera, Rafael Fern\u00e1ndez-Gal\u00e1n, Amparo Serrano, Elena Villase\u00f1or: Synthesis, Characterization and Reactivity of New Dinuclear Guanidinate Diimidoniobium Complexes<\/em>. European Journal of Inorganic Chemistry 06\/2013; 2013(16):1940. DOI:10.1002\/ejic.201300025<\/div>\n<\/li>\n
  47. \n
    David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Francisco J Su\u00e1rez, Isabel L\u00f3pez-Solera, Rafael Fern\u00e1ndez-Gal\u00e1n, Elena Villase\u00f1or: Asymmetric niobium guanidinates as intermediates in the catalytic guanylation of amines<\/em>. Dalton Transactions 04\/2013; 42(23). DOI:10.1039\/c3dt50477h<\/div>\n<\/li>\n
  48. \n
    Elena Villase\u00f1or, Ruben Gutierrez-Gonzalez, Fernando Carrillo-Hermosilla, Rafael Fernandez-Galan, Isabel Lopez-Solera, Ana Rodr\u00edguez Fern\u00e1ndez-Pacheco, Antonio Antinolo: Neutral Dimethylzirconocene Complexes as Initiators for the Ring\u2010Opening Polymerization of \u03f5\u2010Caprolactone<\/em>. European Journal of Inorganic Chemistry. 03\/2013; 2013(7-7):1184-1196. DOI:10.1002\/ejic.201201096<\/div>\n<\/li>\n
  49. \n
    Rafael Fernandez-Galan, Antonio Antinolo, Fernando Carrillo-Hermosilla, Isabel Lopez-Solera, Antonio Otero, Amparo Serrano-Laguna, Elena Villasenor: Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes<\/em>. Organometallics 12\/2012; 31(23-23):8360-8369. DOI:10.1021\/om300942p<\/div>\n<\/li>\n
  50. \n
    Rocio Garcia-Alvarez, Francisco J. Suarez, Josefina Diez, Pascale Crochet, Victorio Cadierno, Antonio Antinolo, Rafael Fernandez-Galan, Fernando Carrillo-Hermosilla: Ruthenium(II) Arene Complexes with Asymmetrical Guanidinate Ligands: Synthesis, Characterization, and Application in the Base-Free Catalytic Isomerization of Allylic Alcohols<\/em>. Organometallics 12\/2012; 31:8301-8311. DOI:10.1021\/om3009124<\/div>\n<\/li>\n
  51. \n
    Rafael Fernandez-Galan, Antonio Antinolo, Fernando Carrillo-Hermosilla, Isabel Lopez-Solera, Antonio Otero, Amparo Serrano-Laguna, Elena Villasenor: New zirconium and zirconocene guanidinate complexes<\/em>. Journal of Organometallic Chemistry 07\/2012; 711:35-42. DOI:10.1016\/j.jorganchem.2012.03.023<\/div>\n<\/li>\n
  52. \n
    David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Isabel L\u00f3pez-Solera, B\u00e9reng\u00e8re Menot, Rafael Fern\u00e1ndez-Gal\u00e1n, Elena Villase\u00f1or, Antonio Otero: New Alkylimido Niobium Complexes Supported by Guanidinate Ligands: Synthesis, Characterization, and Migratory Insertion Reactions<\/em>. Organometallics 03\/2012; 31(31):1840. DOI:10.1021\/om201192w<\/div>\n<\/li>\n
  53. \n
    Antonio Anti\u00e7olo, Fernando Carrillo-Hermosilla, Victorio Cadierno, Joaqu\u00edn Garc\u00eda-\u008dlvarez, Antonio Otero: Microwave-Assisted Meyer-Schuster Rearrangement of Propargylic Alcohols Catalyzed by the Oxovanadate Complex [V(O)Cl(OEt) 2 ].<\/em>. ChemCatChem 01\/2012; 4(1-2012):123. DOI:10.1002\/cctc.201100239<\/div>\n<\/li>\n
  54. \n
    Javier Romero-Fern\u00e1ndez, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Carlos Alonso-Moreno, Ana M Rodr\u00edguez, Isabel L\u00f3pez-Solera, Antonio Otero: Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines<\/em>. Dalton Transactions 07\/2010; 39(28):6419-25. DOI:10.1039\/c0dt00064g<\/div>\n<\/li>\n
  55. \n
    Carlos Alonso-Moreno, Fernando Carrillo-Hermosilla, Andre\u0301s Garce\u0301s, Antonio Otero, Isabel Lo\u0301pez-Solera, Ana M. Rodri\u0301guez, Antonio Antin\u0303olo: Simple, Versatile, and Efficient Catalysts for Guanylation of Amines<\/em>. Organometallics 05\/2010; 29(12). DOI:10.1021\/om1003122<\/div>\n<\/li>\n
  56. \n
    Carlos Alonso-Moreno, Pedro Carrion, Fernando Carrillo\u2010Hermosilla, Antonio Anti\u00f1olo, Antonio Otero: UV-visible spectroscopy for zirconocene activation by MAO in olefin polymerization: Activity versus wavenumber<\/em>. Applied Organometallic Chemistry 06\/2009; 23(6):241 – 244. DOI:10.1002\/aoc.1505<\/div>\n<\/li>\n
  57. \n
    Javier Romero, Fernando Carrillo-Hermosilla, Antonio Anti\u00f1olo, Antonio Otero: Homogeneous and supported bis(imino)pyridyl vanadium(III) catalysts<\/em>. Journal of Molecular Catalysis A Chemical 05\/2009; 304(1):180-186. DOI:10.1016\/j.molcata.2009.02.010<\/div>\n<\/li>\n
  58. \n
    Carlos Alonso\u2010Moreno, Fernando Carrillo\u2010Hermosilla, Javier Romero\u2010Fern\u00e1ndez, Ana\u2005M. Rodr\u00edguez, Antonio Otero, Antonio Anti\u00f1olo: Well\u2010Defined Regioselective Iminopyridine Rhodium Catalysts for Anti\u2010Markovnikov Addition of Aromatic Primary Amines to 1\u2010Octyne<\/em>. Advanced Synthesis & Catalysis 04\/2009; 351(6):881 – 890. DOI:10.1002\/adsc.200800786<\/div>\n<\/li>\n
  59. \n
    Carlos Alonso-Moreno, Jos\u00e9 Sancho, Fernando Carrillo-Hermosilla, Antonio Otero, Antonio Anti\u00f1olo, Isabel L\u00f3pez-Solera: Synthesis, characterization and compared reactivity of asymmetrical ansa-metallocenes<\/em>. Inorganic Chemistry Communications 02\/2009; 12(2):184-186. DOI:10.1016\/j.inoche.2008.11.032<\/div>\n<\/li>\n
  60. \n
    Pedro J. Arag\u00f3n S\u00e1ez, Fernando Carrillo-Hermosilla, Elena Villase\u00f1or, Antonio Otero, Antonio Anti\u00f1olo, Ana M. Rodr\u00edguez: Heterocycle-Substituted Indenes as Precursors for Supported Zirconocene Catalysts<\/em>. European Journal of Inorganic Chemistry. 01\/2008; 2008(2):330-337. DOI:10.1002\/ejic.200700918<\/div>\n<\/li>\n
  61. \n
    Carlos Alonso-Moreno, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Pedro Carri\u00f3n, Ana M. Rodr\u00edguez, Antonio Otero, Jos\u00e9 Sancho: Activation process of 3-alkyl-substituted ansa-bis(indenyl) zirconocenes by MAO<\/em>. Journal of Molecular Catalysis A Chemical 01\/2007; 261(1):53-63. DOI:10.1016\/j.molcata.2006.07.041<\/div>\n<\/li>\n
  62. \n
    Pedro Carri\u00f3n, Fernando Carrillo-Hermosilla, Carlos Alonso-Moreno, Antonio Otero, Antonio Anti\u00f1olo, Jos\u00e9 Sancho, Elena Villase\u00f1or: Supported modified zirconocene catalyst for ethylene polymerization<\/em>. Journal of Molecular Catalysis A Chemical 10\/2006; 258(1):236-245. DOI:10.1016\/j.molcata.2006.05.055<\/div>\n<\/li>\n
  63. \n
    Carlos Alonso-Moreno, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Antonio Otero, Ana M. Rodr\u00edguez, Jos\u00e9 Sancho, Victoria Volkis, Moris Eisen: Synthesis, Characterization, and Catalytic Properties ofansa-Zirconocenes [Zr{1Me2Si(3-<\/em>\u03b7<\/em>5-C9H5R)2}Cl2] (R = Me,nPr,nBu, and Bz)<\/em>. European Journal of Inorganic Chemistry.\u00a0 03\/2006; 2006(5):972-979. DOI:10.1002\/ejic.200500845<\/div>\n<\/li>\n
  64. \n
    Pedro J. Arag\u00f3n, Fernando Carrillo\u2010Hermosilla, Elena Villase\u00f1or, Antonio Otero, Antonio Anti\u00f1olo, Ana M. Rodr\u00edguez: Synthesis, Structure and Reactivity in Styrene Polymerization by Heterocyclic Alkoxy\u2010 and Thiolatotitanium(IV) Complexes<\/em>. European Journal of Inorganic Chemistry. 03\/2006; 2006(5):965 – 971. DOI:10.1002\/ejic.200500826<\/div>\n<\/li>\n
  65. \n
    Dami\u00e1n P\u00e9rez-Quintanilla, Isabel del Hierro, Fernando Carrillo-Hermosilla, Mariano Fajardo, Isabel Sierra: Adsorption of mercury ions by mercapto-functionalized amorphous silica<\/em>. Analytical and Bioanalytical Chemistry 03\/2006; 384(3):827-38. DOI:10.1007\/s00216-005-0210-7<\/div>\n<\/li>\n
  66. \n
    Carlos Alonso-Moreno, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Pedro Carri\u00f3n, Isabel L\u00f3pez-Solera, Antonio Otero, Sanjiv Prashar, Jos\u00e9 Sancho: Novel Indenylzirconium Complexes as Supported Catalysts in the Polymerization of Ethylene<\/em>. European Journal of Inorganic Chemistry. 07\/2005; 2005(14-14):2924-2934. DOI:10.1002\/ejic.200500165<\/div>\n<\/li>\n
  67. \n
    Carlos Alonso, Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Pedro Carri\u00f3n, Antonio Otero, Jos\u00e9 Sancho, Elena Villase\u00f1or: Modified Silicas as Supports for Single-Site Zirconocene Catalysts<\/em>. Journal of Molecular Catalysis A Chemical 10\/2004; 220(2-2):285-295. DOI:10.1016\/j.molcata.2004.06.012<\/div>\n<\/li>\n
  68. \n
    Isabel del Hierro, Isabel Sierra, Dami\u00e1n P\u00e9rez-Quintanilla, Fernando Carrillo-Hermosilla, Isabel L\u00f3pez-Solera, Mariano Fajardo: Synthesis of adducts from mercury(II) with N and S donor ligands as models of adsorbent materials for the retention of heavy metals<\/em>. Inorganica Chimica Acta 11\/2003; 355:347\u2013353. DOI:10.1016\/S0020-1693(03)00302-5<\/div>\n<\/li>\n
  69. \n
    S Rojas, P Terreros, M.A Pe\u00f1a, M Ojeda, J.L.G Fierro, A Otero, F Carrillo: Hydrogenation of aromatics over supported noble metal catalysts ex organometallic complexes<\/em>. Journal of Molecular Catalysis A Chemical 10\/2003; 206(s 1\u20132):299\u2013311. DOI:10.1016\/S1381-1169(03)00417-5<\/div>\n<\/li>\n
  70. \n
    Antonio Otero, Fernando Carrillo-Hermosilla, Pilar Terreros, Teresa Exp\u00f3sito, Sergio Rojas, Juan Fern\u00e1ndez-Baeza, Antonio Anti\u00f1olo, Isabel L\u00f3pez-Solera: Synthesis, Structure and Reactivity of New Late Transition Metal Complexes Bearing Diphosphane Ligands Derived from Bis(pyrazol\u20101\u2010yl)methane<\/em>. European Journal of Inorganic Chemistry. 09\/2003; 2003(17):3233 – 3241. DOI:10.1002\/ejic.200300202<\/div>\n<\/li>\n
  71. \n
    A Otero, J Fern\u00e1ndez-Baeza, A Anti\u00f1olo, F Carrillo-Hermosilla, J Tejeda, A Lara-S\u00e1nchez, L. F. S\u00e1nchez-Barba, M Fern\u00e1ndez-L\u00f3pez, and A. M. Rodr\u00edguez, I L\u00f3pez-Solera: Preparation of New Monoanionic \u201cScorpionate\u201d Ligands: Synthesis and Structural Characterization of Titanium(IV) Complexes Bearing This Class of Ligand<\/em>. Inorganic Chemistry 11\/2002; 41(20):5193-202. DOI:10.1021\/ic020319f<\/div>\n<\/li>\n
  72. \n
    A Otero, J Fernandez-Baeza, A Antinolo, F Carrillo-Hermosilla, J Tejeda, A Lara-Sanchez, I Lopez-Solera: Synthesis and spectroscopic characterization of \u03b1-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [Cp*ZrCl3(2-TCMP)], Cp*=\u03b75-C5Me5, 2-TCMP=[{2-thiazolylcarbonyl}methylene]triphenylphosphorane<\/em>. Journal of Organometallic Chemistry 06\/2001; 629(1-2-1-2):68-76. DOI:10.1016\/S0022-328X(01)00815-4<\/div>\n<\/li>\n
  73. \n
    Otero, J. Fern\u00e1ndez-Baeza, A. Anti\u00f1olo, F. Carrillo-Hermosilla, J. Tejeda, E. D\u00edez-Barra, A. Lara-Sanchez, L. Sanchez-Barba, I. L\u00f3pez-Solera: Polymerization of Ethylene by the Electrophilic Heteroscorpionate-Containing Complexes [TiCl3(bdmpza)] and [TiCl2(bdmpza){O(CH2)4Cl}] (bdmpza = Bis(3,5-dimethylpyrazol-1-yl)acetate)<\/em>. Organometallics 05\/2001; 20(12). DOI:10.1021\/om0008777<\/div>\n<\/li>\n
  74. \n
    Michelle Jezequel, V\u00e9ronique Dufaud, Maria Jos\u00e9 Ruiz-Garcia, Fernando Carrillo-Hermosilla, Ute Neugebauer, Gerald P. Niccolai, Fr\u00e9d\u00e9ric Lefebvre, Fran\u00e7ois Bayard, Judith Corker, Steven Fiddy, John Evans, J P Broyer, Jean Malinge, J M Basset: Supported Metallocene Catalysts by Surface Organometallic Chemistry. Synthesis, Characterization, and Reactivity in Ethylene Polymerization of Oxide-Supported Mono- and Biscyclopentadienyl Zirconium Alkyl Complexes: Establishment of Structure\/Reactivity Relationships<\/em>. Journal of the American Chemical Society 05\/2001; 123(15):3520-40. DOI:10.1021\/ja000682q<\/div>\n<\/li>\n
  75. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Juan Fern\u00e1ndez-Baeza, Antonio Otero, Javier S\u00e1nchez-Prada, Elena Villase\u00f1or: Studies on the reactivity of Nb(eta(5)-C5H4SiMe3)(2)(X)(L), X = H,Cl; L = CNXylyl, CNCy, CO and Nb(eta(5)-C5H4SiMe3)(2)(H)(3) complexes toward the Lewis acids B(C6F5)(3) and BF3<\/em>. Journal of Organometallic Chemistry 09\/2000; 609(s 1\u20132):123\u2013129. DOI:10.1016\/S0022-328X(00)00107-8<\/div>\n<\/li>\n
  76. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Juan Fern\u00e1ndez-Baeza, Santiago Garc\u00eda-Yuste, Antonio Otero, Ana Mar\u00eda Rodr\u00edguez, Javier S\u00e1nchez-Prada, Elena Villase\u00f1or, Ricard Gelabert, Miquel Moreno, Jos\u00e9 M. Lluch, Agust\u00ed Lled\u00f3s: Structure and dynamics of [Nb(eta(C5H4SiMe3)-C-5)(2)(eta(2)-H2BR2)] (R-2 = O2C6H4, C8H14, H-2) complexes. A combined experimental and theoretical study<\/em>. Organometallics 08\/2000; 19(18). DOI:10.1021\/om000221d<\/div>\n<\/li>\n
  77. \n
    A Antinolo, F Carrillo-Hermosilla, A Corrochano, J Fernandez-Baeza, A Lara-Sanchez, MR Ribeiro, M Lanfranchi, A Otero, MA Pellinghelli, MF Portela, JV Santos: Synthesis of zirconium(IV) monocyclopentadienyl-aryloxy complexes and their use in catalytic ethylene polymerization. X-ray structure of (eta(5)-C5Me5)Zr{2,6-OC6H3(CH3)(2)}(3)<\/em>. Organometallics 07\/2000; 19(15):2837-2843. DOI:10.1021\/om0002091<\/div>\n<\/li>\n
  78. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Juan Fern\u00e1ndez-Baeza, Santiago Garc\u00eda-Yuste, Antonio Otero, Javier S\u00e1nchez-Prada, Elena Villase\u00f1or: New Studies on the Reactivity of Hydride-Containing Niobocene Complexes Towards Insertion and Protonation Processes<\/em>. European Journal of Inorganic Chemistry 2000, 1437-1443.\u00a0 DOI: 10.1002\/1099-0682(200007)2000:7<1437::AID-EJIC1437>3.0.CO;2-J.<\/div>\n<\/li>\n
  79. \n
    Anti\u00f1olo, F. Carrillo-Hermosilla, J. Fern\u00e1ndez-Baeza, S. Garc\u00cda-Yuste, A. Otero, E. Palomares, A. M. Rodriguez, L. F. S\u00e1nchez-Barba: Studies on the reactivity of alkoxo-niobium(V) compounds towards O, O- or S, S-enolate ligands. Synthesis and structural characterisation of (alkoxo)(\u03b2-diketonato)- and (alkoxo)[dialkyl(aryl)dithiocarbamato] complexes of niobium(V)<\/em>. Journal of Organometallic Chemistry 05\/2000; 603(2):194-202. DOI:10.1016\/S0022-328X(00)00168-<\/div>\n<\/li>\n
  80. \n
    A Antinolo, F Carrillo-Hermosilla, J Fernandez-Baeza, AMF de Toro, S Garcia-Yuste, A Otero, JC Perez-Flores, AM Rodriguez: Synthesis and characterization of thiolate, -amido, and -oxy heterocyclic-containing niobocene complexes: X-ray molecular studies of [Nb(\u03b75-C5H4SiMe3)2(\u03b72-N,S-S(C6H7N2))] (3)<\/em>. Inorganica Chimica Acta 04\/2000; 300:131-137. DOI:10.1016\/S0020-1693(99)00482-X<\/div>\n<\/li>\n
  81. \n
    Anti\u00f1olo, P. Ca\u00f1izares, F. Carrillo-Hermosilla, J. Fern\u00e1ndez-Baeza, F.J. F\u00fanez, A. de Lucas, A. Otero, L. Rodr\u00cdguez, J.L. Valverde: A grafted methane partial oxidation catalyst from MoO2(acac)2 and HZSM-5 zeolite<\/em>. Applied Catalysis A: General. 2\/2000; 193:1-2, 139-146. DOI: 10.1016\/S0926-860X(99)00423-8.<\/div>\n<\/li>\n
  82. \n
    Anton\u00edo Otero, Juan Fern\u00e1ndez-Baeza, JB Tejeda, Anton\u00edo Anti\u00f1olo, Fernando Carrillo-Hermosilla, Enrique D\u00edez-Barra, Agustin Lara-S\u00e1nchez, Mar\u00eda Fern\u00e1ndez-L\u00f3pez: A new type of monoanionic \u00abscorpionate\u00bb ligand. <\/em>Synthesis, spectroscopic characterisation and dynamic behaviour of some niobium(III) complexes<\/em>. Organometallics 01\/2000; 14(14-14):2367-2374. DOI:10.1039\/b002742l<\/div>\n<\/li>\n
  83. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Elena Corrochano, Rosa Fandos, Juan Fern\u00e1ndez-Baeza, Ana Mar\u00eda Rodr\u00edguez, Mar\u00eda Jos\u00e9 Ruiz, Antonio Otero: New Monocyclopentadienyl Complexes of Titanium(IV) and Zirconium(IV) with Chelating Pyrimidinethiolate, Oxypyrimidine, and Oxypyridine Ligands. Molecular Structure of [Zr(\u03b75-C5Me5)(\u03b72-O,N-ON2C6H7)3]<\/em>. Organometallics 12\/1999; 18(25):5219-5224. DOI:10.1021\/om990335t<\/div>\n<\/li>\n
  84. \n
    A Otero, J Fernandez-Baeza, J Tejeda, A Antinolo, F Carrillo-Hermosilla, E Diez-Barra, A Lara-Sanchez, M Fernandez-Lopez, M Lanfranchi, MA Pellinghelli: Syntheses and crystal structures of lithium and niobium complexes containing a new type of monoanionic \u00abscorpionate\u00bb ligand<\/em>. Organometallics 10\/1999; DOI:10.1039\/a907505d<\/div>\n<\/li>\n
  85. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Mariano Fajardo, Juan Fern\u00e1ndez-Baeza, Santiago Garc\u00cda-Yuste, Antonio Otero: Advances in the chemistry of bis-cyclopentadienyl hydride derivatives of niobium and tantalum<\/em>. Coordination Chemistry Reviews 10\/1999; 193-5:43-72. DOI:10.1016\/S0010-8545(99)00164-2<\/div>\n<\/li>\n
  86. \n
    A Antinolo, F Carrillo-Hermosilla, A.E. Corrochano, J Fernandez-Baeza, M Lanfranchi, A Otero, M.A. Pellinghelli: Synthesis of new oxy and thiolate [hydro-tris(pyrazol-1-yl)borato] titanium and zirconium(IV) complexes. Molecular structure of [Ti(HB(3,5-Me(2)pz)(3))Cl-3]<\/em>. Journal of Organometallic Chemistry 04\/1999; 577(2-2):174-180. DOI:10.1016\/S0022-328X(98)01015-8<\/div>\n<\/li>\n
  87. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Enrique D\u00edez-Barra, Juan Fern\u00e1ndez-Baeza, Maria Fern\u00e1ndez-L\u00f3pez, Agustin Lara-S\u00e1nchez, Andr\u00e9s Moreno, Antonio Otero, AM Rodriguez, Juan Tejeda: New functionalized bis(pyrazol-1-yl)methane ligands, Synthesis, spectroscopic characterization of early and late transition metal complexes containing a functionalized N,N or P,P-chelate bis(5-diphenylphosphinopyrazol-1-yl)methane ligand<\/em>. Journal of the Chemical Society, Dalton Transactions. 11\/1998; 3737-3744.\u00a0DOI:10.1039\/a805683h<\/div>\n<\/li>\n
  88. \n
    A Antinolo, F Carrillo-Hermosilla, E Diez-Barra, J Fernandez-Baeza, A Lara-Sanchez, A Otero, J Tejeda: Phosphorus ylide-containing niobium complexes: Preparation and characterization of homo- and heteronuclear compounds with an \u03b1-keto ylide ligand<\/em>. Journal of Organometallic Chemistry 11\/1998; 570(1-1):97-105. DOI:10.1016\/S0022-328X(98)00811-0<\/div>\n<\/li>\n
  89. \n
    Anti\u00f1olo, F. Carrillo-Hermosilla, J. Fern\u00e1ndez-Baeza, M. Lanfranchi, A. Lara-S\u00e1nchez, A. Otero, E. Palomares, MA Pellinghelli, A. M. Rodriguez: Synthesis and Characterization of New Niobium Hydridotris(3,5-dimethylpyrazol-1-yl)borato Complexes<\/em>. Organometallics 06\/1998; 17(14). DOI:10.1021\/om971130s<\/div>\n<\/li>\n
  90. \n
    Anti\u00f1olo, F. Carrillo-Hermosilla, A. Castel, M. Fajardo, J. Fern\u00e1ndez-Baeza, M. Lanfranchi, A. Otero, MA Pellinghelli, G. Rima, J. Satg\u00e9, E. Villase\u00f1or: Synthesis and Characterization of the First Niobocene Germyl Complexes and Reactivity of Triphenylsilyl-, Triphenylgermyl-, and Triphenylstannylniobocene Derivatives. X-ray Molecular Structures of d0 Nb(\u03b75 -C5H4SiMe3)2(H)2(EPh3) (E = Ge, Sn)<\/em>. Organometallics 04\/1998; 17(8):1523-1529. DOI:10.1021\/om971001b<\/div>\n<\/li>\n
  91. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Antonio Otero, Mariano Fajardo, Andr\u00e9s Garc\u00e9s, Pilar G\u00f3mez-Sal, Carmen L\u00f3pez-Mardomingo, Avelino Mart\u00edn, Carlos Miranda: Synthesis and structural characterization of isocyanate, amido and imido niobocene derivatives: Crystal structures of [Nb(\u03b75-C5H4Si-Me3) 2Cl\u03ba2N,C-OCNPh] and [{Nb(\u03b75-C5H4SiMe3) 2Cl}2-(\u03bc-1,3-N2C6H4)]<\/em>. Journal of the Chemical Society Dalton Transactions 01\/1998; DOI:10.1039\/A705352E<\/div>\n<\/li>\n
  92. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Isabel del Hierro, Antonio Otero: Synthesis and Characterization of New Alkyl\u2212Carbon Dioxide Compounds and the First Neutral Acyl\u2212Carbonyl Niobocene Complexes<\/em>. Organometallics 09\/1997; 16(19). DOI:10.1021\/om9702643<\/div>\n<\/li>\n
  93. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Mariano Fajardo, Santiago Garcia-Yuste, Antonio Otero, Santiago Camanyes, Feliu Maseras, Miquel Moreno, Agust\u00ed Lled\u00f3s, and Jos\u00e9 M. Lluch: Synthesis and Spectroscopic Properties of Dihydrogen Isocyanide Niobocene [Nb(\u03b7 5 -C 5 H 4 SiMe 3 ) 2 (\u03b7 2 -H 2 )(CNR)] + Complexes. Experimental and Theoretical Study of the Blocked Rotation of a Coordinated Dihydrogen<\/em>. Journal of the American Chemical Society 07\/1997; 119(26):6107-6114. DOI:10.1021\/ja9640354<\/div>\n<\/li>\n
  94. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Santiago Garcia-Yuste, Manuel Freitas, Antonio Otero, Sanjiv Prashar, Elena Villase\u00f1or, Mariano Fajardo: Insertion reactions of heterocumulenes into the niobium-hydride bond of isocyanide and carbonyl niobocene complexes<\/em>. Inorganica Chimica Acta 06\/1997; 259(1-2):101-105. DOI:10.1016\/S0020-1693(96)05587-9<\/div>\n<\/li>\n
  95. \n
    Antonio Anti\u00f1olo, Fernando Carrillo-Hermosilla, Mariano Fajardo, Santiago Garc\u00eda-Yuste, Maurizio Lanfranchi, Antonio Otero, Maria Angela Pellinghelli, Sanjiv Prashar, Elena Villase\u00f1or: Studies on the insertion reactions of activated alkynes into Nb-H bonds in hydride-niobocene complexes. X-ray crystal structures of Nb(\u03b75-C5H4SiMe3) 2(H)[\u03b72-RO2C(H)=C(H)CO2R] (R = Me or tBu)<\/em>. Organometallics 12\/1996; 15(26-26). DOI:10.1021\/om960524<\/div>\n<\/li>\n
  96. \n
    Antonio Anti\u00f1olo,, Fernando Carrillo-Hermosilla,, Bruno Chaudret,, Mariano Fajardo,, Juan Fern\u00e1ndez-Baeza,, Maurizio Lanfranchi,, Hans-Heinrich Limbach,, Markus Maurer,, Antonio Otero, and Maria Angela Pellinghelli: Exchange Coupling in Niobocene Trihydrides, Nb(C5H3RR\u2018)2H3, and Their Adducts with Copper Triad Cations, [{Nb(C5H3RR\u2018)2H3}2M]+ (R = R\u2018 = H; R = H, R\u2018= SiMe3; R = R\u2018 = SiMe3; M = Cu, Ag, Au)<\/em>. Inorganic Chemistry 12\/1996; 35(26). DOI:10.1021\/ic960582e<\/div>\n<\/li>\n
  97. \n
    Carrillo-Hermosilla, F.A. Jalon, A. Otero, E. Villase\u00f1or: Synthesis and structural characterization of pyrazole and pyrazolyl niobocene complexes<\/em>. Anales de qu\u00edmica,\u00a0Int. Ed.\u00a0\/ v.92 no.6. 1996, pp.339-343Antonio Antinolo, Fernando Carrillo, Mariano Fajardo, Antonio Otero, Mauricio Lanfranchi, Maria Angela Pellinghelli: Synthesis and Characterization of New Silyl Niobocene Complexes. <\/em>X-ray Molecular Structure of d.degree. Nb(.eta.5-C5H4SiMe3)2(H)2(SiPh2H)<\/em>. Organometallics 03\/1995; 14(3):1518-1521. DOI:10.1021\/om00003a064<\/div>\n<\/li>\n
  98. \n
    Antonio Antinolo, Fernando Carrillo, Bruno Chaudret, Mariano Fajardo, S GARCIA YUSTE, FJ LAHOZ, Maurizio Lanfranchi, JA LOPEZ, Antonio Otero, MA PELLINGHELLI: SYNTHESIS OF COINAGE METAL CATION ADDUCTS OF NB(C(5)H(4)SIME(3))(2)H(CO) – X-RAY CRYSTAL-STRUCTURE OF [(NB(C(5)H(4)SIME(3))(2)(CO))2(MU-H)(2)CU]PF6<\/em>. Organometallics 03\/1995; 14(3-3):1297-1301. DOI:10.1021\/om00003a033<\/div>\n<\/li>\n
  99. \n
    Antonio Antinolo, Fernando Carrillo, Bruno Chaudret, Mariano Fajardo, J FERNANDEZBAEZA, Maurizio Lanfranchi, HH LIMBACH, Markus Maurer, Antonio Otero, MA PELLINGHELLI: Synthesis, Spectroscopic Properties, and X-ray Crystal Structure of {[Nb(C5H3[SiMe3]2)2H3]2Au}+, a Complex Showing Large Quantum Mechanical Exchange Couplings<\/em>. Inorganic Chemistry 11\/1994; 33(23-23):5163-5164. DOI:10.1021\/ic00101a002<\/div>\n<\/li>\n
  100. \n
    Antonio Anti\u00f1olo, Fernando Carrillo, Mariano Fajardo, S Garc\u00eda-Yuste, Antonio Otero: Studies of the reactivity towards insertion and electrophilic processes of Nb-H and Nb(\u03b72-CS2) moieties of bis(trimethylsilylcyclopentadienyl)niobium complexes<\/em>. Journal of Organometallic Chemistry 11\/1994; 482(1-2-1-2):93-98. DOI:10.1016\/0022-328X(94)88189-8<\/div>\n<\/li>\n
  101. \n
    Antonio Anti\u00f1olo, Fernando Carrillo, Santiago Garcia-Yuste, Antonio Otero: Studies on the Reaction between Bis((trimethylsilyl)cyclopentadienyl)niobium Trihydride and Styrene<\/em>. Organometallics 07\/1994; 13(7). DOI:10.1021\/om00019a036<\/div>\n<\/li>\n
  102. \n
    Antonio Anti\u00f1olo, Fernando Carrillo, J Fern\u00e1ndez-Baeza, Antonio Otero, Mariano Fajardo, Bruno Chaudret: Exchange couplings in Lewis acid adducts of substituted niobocene trihydrides<\/em>. Inorganic Chemistry 12\/1992; 31(25-25):5156-5157. DOI:10.1021\/ic00051a001<\/div>\n<\/li>\n<\/ol>\n<\/div>\n<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"

    La investigaci\u00f3n desarrollada en nuestros laboratorios se lleva a cabo gracias a las ayudas de MICIU\/AEI\/10.13039\/501100011033 (Proyectos PID2020-117353GB-I00 y RED2022-134287-T), Junta de Comunidades de Castilla-La Mancha y la Uni\u00f3n Europea a trav\u00e9s del programa FEDER (Proyecto SBPLY\/23\/180225\/000021), y la Universidad de Castilla-La Mancha (Proyecto 2022-GRIN-34031). INVESTIGACI\u00d3N Mi investigaci\u00f3n se ha movido mucho a lo largo […]<\/p>\n","protected":false},"author":58,"featured_media":589,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"open","template":"","meta":{"footnotes":""},"class_list":["post-78","page","type-page","status-publish","has-post-thumbnail","hentry"],"_links":{"self":[{"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/pages\/78","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/users\/58"}],"replies":[{"embeddable":true,"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/comments?post=78"}],"version-history":[{"count":45,"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/pages\/78\/revisions"}],"predecessor-version":[{"id":1422,"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/pages\/78\/revisions\/1422"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/media\/589"}],"wp:attachment":[{"href":"https:\/\/blog.uclm.es\/fernandocarrillo\/wp-json\/wp\/v2\/media?parent=78"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}