Publicaciones

Publicaciones
2011-2018
Ramos, Alberto;  Antinolo, Antonio; Carrillo-Hermosilla, Fernando;  Fernandez-Galan, Rafael; Rodriguez-Dieguez, Antonio; Garcia-Vivo, Daniel. Carbodiimides as catalysts for the reduction of CO2 with boranes. CHEMICAL COMMUNICATIONS 2018, 544700-4703
DOI 10.1039/c8cc02139b
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Bravo, Ivan; Garzon-Ruiz, Andres; Alonso-Moreno, Carlos;  Carrillo-Hermosilla, Fernando; Antinolo, Antonio;  Albaladejo, Jose. Guanidine Substitutions in Naphthyl Systems to Allow a Controlled Excited-State Intermolecular Proton Transfer: Tuning Photophysical  Properties in Aqueous Solution. JOURNAL OF PHYSICAL CHEMISTRY 2018, 122, 9363-9373.
DOI: 10.1021/acs.jpcc.8b02576
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Martinez, Antonio; Moreno-Blazquez, Sonia; Rodriguez-Dieguez, Antonio; Ramos, Alberto; Fernandez-Galan, Rafael; Antinolo, Antonio; Carrillo-Hermosilla, Fernando. Simple ZnEt2 as a catalyst in carbodiimide hydroalkynylation: structural and mechanistic studies. Dalton Trans., 2017,46, 12923-12934.
DOI: 10.1039/c7dt02700a
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Ramos, Alberto;   Antiñolo, Antonio;   Carrillo-Hermosilla, Fernando; Fernandez-Galan, Rafael;   Montero-Rama, Maria del Pilar;  Villasenor, Elena; Rodriguez-Dieguez, Antonio; Garcia-Vivo, Daniel. Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates.Dalton Trans., 2017,46, 10281-10299
DOI: 10.1039/c7dt02081
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De Tullio, Marco; Hernán-Gómez, Alberto; Livingstone, Zoe; Clegg, William; Kennedy, Alan R.; Harrington,Ross W.; Antiñolo, Antonio; Martinez, Antonio; Carrillo-Hermosilla, Fernando; Hevia, Eva. Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines. Chem. Eur. J. 2016, 22, 17646 – 17656. DOI: 10.1002/chem.201602906

Antiñolo, Antonio; Carrillo-Hermosilla, Fernando; Fernández-Galán, Rafael; Pilar Montero-Rama, Maria; Ramos, Alberto; Villaseñor, Elena; Rojas, Rene S.; Rodriguez-Dieguez, Antonio.Dialkylboron guanidinates: syntheses, structures and carbodiimide de-insertion reactions. Dalton Trans., 2016,45, 15350-15363. DOI: 10.1039/c6dt02913b

Antiñolo, Antonio; Carrillo-Hermosilla, Fernando; Fernández-Galán, Rafael; Martínez-Ferrer, Jaime;Alonso-Moreno, Carlos; Bravo, Ivan; Moreno-Blázquez, Sonia; Salgado, Manuel; Villaseñor, Elena; Albaladejo, José. Tris(pentafluorophenyl)borane as an efficient catalyst in the guanylation reaction of amines. Dalton Trans., 2016,45, 10717-10729. DOI: 10.1039/C6DT01237J

Francos, Javier; Gonzalez-Liste, Pedro J.; Menendez-Rodriguez, Lucia; Crochet, Pascale; Cadierno, Victorio; Borge, Javier; Antinolo, Antonio; Fernández-Galán, Rafael; Carrillo-Hermosilla, Fernando.Half-Sandwich Guanidinate-Osmium(II) Complexes: Synthesis and Application in the Selective Dehydration of Aldoximes. Eur. J. Inorg. Chem., 2016, 393–402. DOI: 10.1002/ejic.201501221

Daniel Nieto; Sonia Bruna; Ana Ma Gonzalez-Vadillo; Josefina Perles; Fernando Carrillo-Hermosilla; Antonio Antinolo; Jose M. Padron; Gabriela B. Plata; Isabel Cuadrado. Catalytically Generated Ferrocene-Containing Guanidines as Efficient Precursors for New Redox-Active Heterometallic Platinum(II) Complexes with Anticancer Activity. ORGANOMETALLICS. 34 – 22, pp. 5407 – 5417. 11/2015. ISSN 0276-7333. DOI: 10.1021/acs.organomet.5b00751

Ivan Bravo; Carlos Alonso-Moreno; Fernando Carrillo-Hermosilla; Isabel Lopez-Solera; Antonio Antinolo; Jose Albaladejo. Toward the Prediction of Activity in the Ethylene Polymerisation of ansa-Bis(indenyl) Zirconocenes: Effect of the Stereochemistry and Hydrogenation of the Indenyl Moiety. CHEMPLUSCHEM. 80 – 6, pp. 963 – 972. 06/2015. ISSN 2192-6506.

Lucia Menendez Rodriguez; Eder Tomás Mendivil; Javier Francos; Pascale Crochet; Victorio Cadierno; Antonio Antiñolo; Rafael Fernandez Galan; Fernando Carrillo Hermosilla. Reactivity of the Dimer [{RuCl(μ-Cl)(η3:η3‑C10H16)}2] (C10H16 = 2,7-Dimethylocta-2,6-diene-1,8-diyl) toward Guanidines: Access toRuthenium(IV) and Ruthenium(II) Guanidinate Complexes. Organometallics. 34, pp. 2796 – 2809. ACS, 20/05/2015.

Antonio Antiñolo; Santiago García Yuste; Antonio Otero; Arturo Espinosa. Unusual Mechanism for the Reaction of a Niobocene HydrideComplex with Activated Alkynes. Experimental and DFT Studies. ORGANOMETALLICS. 34, pp. 2695 – 2698. acs, 12/01/2015.

David Elorriaga; Fernando Carrillo-Hermosilla; Antonio Antiñolo; Isabel López-Solera; Rafael Fernandez-Galan; Elena Villaseñor. Mixed amido-/imido-/guanidinato niobium complexes: synthesis and the effect of ligands on insertion reactions. Dalton Transactions. 43, pp. 17434 – 17444. Royal Society of Chemistry, 22/09/2014.

Alan R. Cabrera; Elena Villasenor; Francisca Werlinger; Rene S. Rojas; Mauricio Valderrama; Antonio Antinolo; Fernando Carrillo-Hermosilla; Rafael Fernadez-Galan. {Grafting of the zirconium complexes {[}Zr(eta(5)-C5H5)\{NC-amidine\}-Cl-2] and {[}Zr(eta(5)-C5H5)(NC-NacNac)Cl-2] and the study of their behavior in ethylene polymerization}. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL. 391, pp. 130 – 138. 09/2014. ISSN 1381-1169

Carlos Alonso-Moreno; Antonio Antinolo; Fernando Carrillo-Hermosilla; Antonio Otero. Guanidines: from classical approaches to efficient catalytic syntheses. CHEMICAL SOCIETY REVIEWS. 43 – 10, pp. 3406 – 3425. 2014. ISSN 0306-0012

Rafael Fernandez-Galan; Juan-Antonio Navarro; Fernando Carrillo-Hermosilla; Antonio Antinolo; Isabel Lopez-Solera; Elena Villasenor. Preparation and Structural Studies of Non-Symmetric Guanidinate-Supported Zirconium Complexes. AUSTRALIAN JOURNAL OF CHEMISTRY. 67 – 7, pp. 1063 – 1070. 2014. ISSN 0004-9425

David Elorriaga , Fernando Carrillo-Hermosilla, Antonio Antiñolo, Isabel López-Solera, Rafael Fernández-Galán, and Elena Villaseñor“Unexpected mild C–N bond cleavage mediated by guanidine coordination to a niobium iminocarbamoyl complex.”
Chem. Commun., 2013,49, 8701

Elena Villaseñor, Rubén Gutierrez-Gonzalez, Fernando Carrillo-Hermosilla, Rafael Fernández-Galán,
Isabel López-Solera, Ana Rodríguez Fernández-Pacheco, and Antonio Antiñolo
Neutral Dimethylzirconocene Complexes as Initiators for the Ring-Opening Polymerization of ε-Caprolactone
Eur. J. Inorg. Chem 2013, 1184–1196

Antonio Antiñolo, Juan-Carlos Pérez-Flores, Maria Jesús Hervás, Santiago García-Yuste, Maria Isabel López-Solera, Antonio Otero, Ana Rodríguez Fernández-Pacheco,and Maria Teresa Tercero-Morales
Synthesis and Reactivity of New Niobocene Hydride-Stibine and Hydride-Stilbene Complexes. X-ray Crystal Structure of [Nb(η5-C5H4SiMe3)2(H)(trans-η2-C,C-PhCH=CHPh)]
Organometallics, 2013, 32, 862-868

David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Antiñolo, Isabel López-Solera, Rafael Fernández-Galán, Amparo Serrano and Elena Villaseñor.
“Synthesis, Characterization and Reactivity of New Dinuclear Guanidinate Diimidoniobium Complexes” Eur. J. Inorg. Chem 2013 , 2940-2946

David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Antiñolo, Francisco J. Suárez, Rafael Fernández-Galán, Isabel López-Solera and Elena Villaseñor
“Asymmetric Niobium Guanidinates as Intermediates in the Catalytic Guanylation of Amines.” Dalton Trans., 2013, 42, 8223-8230

Rocío Garcıá -Álvarez, Francisco J. Suaŕez, Josefina Dıéz, Pascale Crochet, Victorio Cadierno, Antonio Antiñolo, Rafael Fernández-Galán, and Fernando Carrillo-Hermosilla
“Ruthenium(II) Arene Complexes with Asymmetrical Guanidinate Ligands: Synthesis, Characterization, and Application in the Base- Free Catalytic Isomerization of Allylic Alcohols” Organometallics 2012, 31, 8301−8311

Rafael Fernández-Galán, Antonio Antiñolo, Fernando Carrillo-Hermosilla, Isabel López-Solera, Antonio Otero, Amparo Serrano-Laguna, and Elena Villaseñor
“Migratory Insertion Reactions in Asymmetrical Guanidinate-Supported Zirconium Complexes” Organometallics, 2012, 31, 8360–8369

Rafael Fernández-Galán, Antonio Antiñolo, Fernando Carrillo-Hermosilla, Isabel López-Solera, Antonio Otero, Amparo Serrano-Laguna and Elena Villaseñor “New Zirconium and Zirconocene Guanidinate Complexes” Journal of Organometallic Chemistry 711(2012) 35-42

Antonio Antiñolo, Khédidja Dorani, Santiago García-Yuste, Isabel López-Solera, Antonio Otero,María Teresa Tercero-Morales, Gábor Kovács, Gregori Ujaque, Agustí Lledós
“Experimental and Theoretical Studies of the Hydrogenation of α,β-Unsaturated Acids by an 18e Hydridecarbonyl niobocene Complex” Organometallics, 2012, 31, 5177-5184

Carlos Alonso-Moreno, Antonio Antiñolo, Santiago García-Yuste, Isabel López-Solera, Antonio Otero,María Teresa Tercero-Morales
Molecular Structure of a Hydrideniobocene Complex [Nb(h5-C5H4SiMe3)2(H)3], and their Use as Catalyst for Ring-Opening Polymerization of Cyclic Esters
Eur. J. Inorg. Chem. 2012, 1139-1144

David Elorriaga, Fernando Carrillo-Hermosilla, Antonio Antiñolo, Isabel López-Solera, Bérengère Menot, Rafael Fernández-Galán, Elena Villaseñor, Antonio Otero.
“New Alkyl Imido Niobium Complexes Supported by Guanidinate Ligands: Synthesis, Characterization and Migratory Insertion Reactions” Organometallics, 2012, 31, 1840-1848

Antonio Antiñolo, Fernando Carrillo-Hermosilla, Victorio Cadierno, Joaquín García-Álvarez, and Antonio Otero
“MW-assisted Meyer-Schuster rearrangement of propargylic alcohols catalyzed by the oxovanadate complex [V(O)Cl(OEt)2]” ChemCatChem 2012, 4, 123 – 128

R. Reguillo-Carmona, A. Antiñolo, S. García-Yuste, I. López-Solera y A. Otero
Lewis base character of the phosphorus atom in phosphanido-niobocene complexes. Synthesis of new early–early homo- and heterobimetallic entities
Dalton Trans., 2011, 40, 2622–2630

2001-2010
161.-Antonio Antiñolo, Santiago García-Yuste, Isabel Lopez Solera, Antonio Otero, Juan Carlos Pérez-Flores, Rebeca Reguillo-Carmona, Elena Villaseñor, Eva Santos, Erik Zuidema and Carles Bo.
Reactions of alkynes with phosphido niobocenes: a combined experimental and theoretical study
Dalton Trans., 2010, 39, 1962–1971

160.-Carlos Alonso-Moreno, Fernando Carrillo-Hermosilla, Andres Garces, Antonio Otero, Isabel Lopez-Solera, Ana M. Rodríguez and Antonio Antiñolo.
Simple, Versatile, and Efficient Catalysts for Guanylation of Amines
Organometallics 2010, 29, 2789–2795

159.-Javier Romero-Fernandez, Fernando Carrillo-Hermosilla, Antonio Antiñolo,Carlos Alonso-Moreno,
Ana M. Rodríguez, Isabel López-Solera and Antonio Otero
Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines
Dalton Trans., 2010, 39, 6419–6425

158.- Antonio Antiñolo, Santiago García-Yuste, Antonio Otero, Rebeca Reguillo-Carmona“An easy and direct synthetic route to phosphamido niobocenes through nucleophilic attack of phosphide niobocene complexes on acyl halides
C. R. Chimie 13 (2010) 929–934

157.- S. Gómez-Ruiz, A. Garcés, S. Prashar, M. Fajardo, A. Antiñolo, A. Otero,
Synthesis,characterization and applications in ethylene polymerization of asymmetric ansa-titanocene complexes. Molecular structure of [Ti{Me2Si(η 5-C5Me4)(η 5-C5H3 iPr}Cl2],
Inorg. Chim. Acta 2009, 362, 1042-1046

156.- Antonio Antiñolo, Santiago García-Yuste, Antonio Otero, Rebeca Reguillo-Carmona
“Insertion Reactions of Isothiocyanates into the Nb–P Bond of Phosphide-Niobocene Complexes”.
Eur. J. Inorg. Chem. 2009, 539-544

155.-Carlos Alonso-Moreno, José Sancho, Fernando Carrillo-Hermosilla, Antonio Otero, Antonio Antiñolo, Isabel López-Solera
Synthesis, Characterization and Compared Reactivity of Asymmetrical ansa-Metallocenes
Inorganic Chemistry Communications, 2009,12, 184-186

154.- Antonio Otero , Juan Fernández-Baeza a, Antonio Antiñolo , Juan Tejeda , Agustín Lara-Sánchez a, Luis F. Sánchez-Barba, Margarita Sánchez-Molina , Carles Bo, Manuel Urbano-Cuadrado
Hybrid scorpionate/cyclopentadienyl titanium and zirconium complexes with alkoxide and imido ligands
Inorganica Chimica Acta 362 (2009) 2909–2914

153.-Carlos Alonso-Moreno, Fernando Carrillo-Hermosilla, Javier Romero-Fernández, Ana M. Rodríguez, Antonio Otero, Antonio Antiñolo
Well-Defined Regioselective Iminopyridine Rhodium Catalysts for Anti-Markovnikov Addition of Aromatic Primary Amines to 1-Octyne
Adv. Synth. Catal. 2009, 351, 881 – 890

152.- Javier Romero, Fernando Carrillo-Hermosilla, Antonio Antiñolo, Antonio Otero
Homogeneous and supported bis(imino)pyridyl vanadium(III) catalysts
Journal of Molecular Catalysis A: Chemical 304 (2009) 180–186

151.-Antonio Antiñolo , Rafael Fernández-Galán , Noelia Molina , Antonio Otero , Iván Rivilla ,Ana M. Rodríguez
New alkenyl-substituted group 4 C-ansa-metallocene complexes. Reactivity of the substituent at the carbon ansa bridge
Journal of Organometallic Chemistry 694 (2009) 1959–1970

150.-Carlos Alonso-Moreno, Pedro Carrión, Fernando Carrillo-Hermosilla, Antonio Antiñolo and Antonio Otero
UV–visible spectroscopy for zirconocene activation by MAO in olefin polymerization: activity versus wavenumber
Appl. Organometal. Chem. 2009 , 23, 241–244

149. – Ortiz, M., Torréns, M., Mola, J.L., Ortiz, P.J., Fragoso, A., Díaz, A., Cao, R., Prados, P., De Mendoza, J., Otero, A., Antiñolo, A., Lara, A.
Nitric oxide binding and photodelivery based on ruthenium (II) complexes of 4-arylazo-3,5-dimethylpyrazole
Dalton Transactions, 2008. 3559-3566

148.- Antonio Otero, Juan Fernández-Baeza, Agustín Lara-Sánchez, Antonio Antiñolo, Juan Tejeda, Emilia Martínez-Caballero, Isabel Márquez-Segovia, Isabel López-Solera, Luis F. Sánchez-Barba, and Carlos Alonso-Moreno.
Versatile Scorpionates and New Developments in the Denticity Changes of NNCp Hybrid Scorpionate/Cyclopentadienyl Ligands in Sc and Y Compounds: From κ1-Nη5-Cp to κ2-NNη5-Cp
Inorg. Chem. 47(2008)4996

147.- Carlos Alonso-Moreno, Andrés Garcés, Luis F. Sánchez-Barba, Mariano Fajardo, Juan Fernández-Baeza, Antonio Otero, Agustín Lara-Sánchez, A. Antiñolo, L. Broomfield, M. I. López-Solera, and A. M. Rodríguez
Discrete Heteroscorpionate Lithium and Zinc Alkyl Complexes. Synthesis, Structural Studies, and ROP of Cyclic Esters
Organometallics 2008, 27, 1310–1321

146.- Pedro J. Aragón Sáez, Fernando Carrillo-Hermosilla, Elena Villaseñor, Antonio Otero, Antonio Antiñolo, and Ana M. Rodríguez
Heterocycle-Substituted Indenes as Precursors for Supported Zirconocene Catalysts
Eur. J. Inorg. Chem. 2008, 330-337

145.-Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Agustín Lara-Sánchez, Emilia Martínez-Caballero, Juan Tejeda,Luis F. Sánchez-Barba, Carlos Alonso-Moreno, and Isabel López-Solera
Scandium and Yttrium Complexes Supported by CNP Heteroscorpionate Ligands: Synthesis, Structure, and Polymerization of e-Caprolactone
Organometallics 2008, 27, 976–983

144.-Luis F. Sanchez-Barba, Andres Garcés, Mariano Fajardo, Carlos Alonso-Moreno, Juan Fernández-Baeza, Antonio Otero, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, and María I. López-Solera
Well-Defined Alkyl Heteroscorpionate Magnesium Complexes as Excellent Initiators for the ROP of Cyclic Esters
Organometallics 2007, 26, 6403-6411

143.- Otero, A., J. Fernandez-Baeza, A. Antinolo, J. Tejeda, A. Lara-Sanchez, L. F. Sanchez-Barba, M. Sanchez-Molina, S. Franco, M. I. Lopez-Solera, A. M. Rodriguez.
Highly diastereoselective nucleophilic addition to myrtenal. Straightforward synthesis of an enantiopure scorpionate ligand.
Inorg. Chem. 46(2007)8475-8477

142.-Santiago Gómez-Ruiz, Dorian Polo-Cerón, Sanjiv Prashar, Mariano Fajardo, Antonio Antiñolo, Antonio Otero
Synthesis and reactivity of alkenyl substituted zirconocene complexes and their application as olefin polymerization catalysts
Eur. J. Inorg. Chem. 2007, 4445–4455

141.- Otero, A; Fernandez-Baeza, J; Antiñolo, A; Tejeda, J; Lara-Sanchez, A; Sanchez-Barba, LF; Sanchez-Molina, M; Rodriguez, AM; Bo, C; Urbano-Cuadrado, M
Expanding heteroscorpionates. Facile synthesis of new hybrid scorpionate/cyclopentadienyl ligands and their lithium and group 4 metal compounds: A combined experimental and density functional theory study
Organometallics 2007, 26, 4310-4320

140.- Antonio Antiñolo, Santiago García-Yuste, Antonio Otero, Elena Villaseñor
On the Insertion Processes of Unsaturated Molecules Into Nb-X sigma Bond of Cp’2NbX Moieties ( Cp’=h5-C5H4SiMe3, X= H, C, P)
J.Organomet. Chem. 692 (2007) 4436–4447

139.-Santiago Gómez-Ruiz a, Sanjiv Prashar, Mariano Fajardo, Antonio Antiñolo, Antonio Otero.
Synthesis, structural characterization and reactivity of new tin bridged ansa-bis(cyclopentadiene) compounds: X-ray crystal structures of Me2Sn(C5Me4R-1)2 (R = H, SiMe3)
J.Organomet. Chem. 692 (2007) 3057-3064

138.-Dorian Polo-Cerón, Santiago Gómez-Ruiz, Sanjiv Prashar, Mariano Fajardo, Antonio Antiñolo and Antonio Otero
“Synthesis Of Bulky Zirconocene Dichloride Compounds And Applications In Olefin Polymerization”
Collect. Czech. Commun. 2007, Vol. 72, Nos. 5–6, pp. 747–763

137.- Antonio Antiñolo, Santiago García-Yuste, Antonio Otero, Juan C. Pérez-Flores, Maria Isabel Lopez-Solera , Ana M. Rodríguez,
“Reactivity of hydride-niobocenes towards heterocycles with hydroxide, -mercapto or -amine functionalities. X-ray molecular structure of [(h5-C5H4SiMe3)2Nb(CNXylyl)2][I3] and [(h5-C5H4SiMe3)2Nb(H)(P(OMe)3)]·(bzta)’-NH2. ((bzta)’-NH2=2-amino-6-methylbenzothiazol)”.
J.Organomet. Chem. 692 (2007) 3328–3339

136.- Antonio Otero, Juan Fernandez-Baeza, Antonio Antiñolo, Juan Tejeda, Agustin Lara-Sánchez, Luis F. Sánchez-Barba, Isabel Lopez-Solera, and Ana M. Rodriguez
“Lithium, Titanium, and Zirconium Complexes with Novel Amidinate Scorpionate Ligands”
Inorg. Chem. 46(2007)1760-1770

135.- Dorian Polo-Cerón a, Santiago Gómez-Ruiz a, Sanjiv Prashar, Mariano Fajardo, Antonio Antiñolo, Antonio Otero, Isabel López-Solera, Manuel L. Reyes.
“Synthesis of chiral unbridged zirconocene complexes: Applications in the polymerization of ethylene and propylene”
Journal of Molecular Catalysis A: Chemical 268 (2007) 264–276

134.-Santiago Gómez-Ruiz a, Sanjiv Prashar, Luis F. Sánchez-Barba, Dorian Polo-Cerón, Mariano Fajardo , Antonio Antiñolo, Antonio Otero, Miguel A. Maestro, César J. Pastor
“Synthesis and catalytic applications of C1 symmetric group 4 ansa-metallocene complexes”
Journal of Molecular Catalysis A: Chemical 264 (2007) 260–269

133.- Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustin Lara-Sánchez, Luis Sánchez-Barba, Margarita Sánchez-Molina, Sonia Franco, Isabel López-Solera and Ana M. Rodríguez
“Design of new heteroscorpionate ligands and their coordinative ability toward Group 4 transition metals; an efficient synthetic route to obtain enantiopure ligands”
Dalton Trans. 2006, 4359-4370

132.- Pedro Carrión, Fernando Carrillo-Hermosilla, Carlos Alonso-Moreno, Antonio Otero, Antonio Antiñolo, José Sancho, Elena Villaseñor
“Supported modified zirconocene catalyst for ethylene polymerization.”
Journal of Molecular Catalysis A: Chemical 258(2006)236-245

131.- Andrés Garcés, Yolanda Pérez , Santiago Gómez-Ruiz, Mariano Fajardo , Antonio Antiñolo , Antonio Otero , Carmen López-Mardomingo , Pilar Gómez-Sal , Sanjiv Prashar,
“Synthesis of Niobocene Imido Cations. X-ray crystal structure of [Nb(=NBut)(η5-C5H4SiMe3)2(CNBut)][BPh4]”
J.Organomet. Chem. 691, 2006, 3652-3658

130. Antonio Antiñolo, David Evrard, Santiago García-Yuste, Antonio Otero, Juan C. Pérez-Flores, Rebeca Reguillo-Carmona, Ana M. Rodríguez, Elena Villaseñor
Synthesis, Reactivity and X-Ray Diffraction Structures of New Isocyanideniobocene Complexes: [Nb(h5-C5H4SiMe3)2(CNR)(PMePh2)]X, R=Xylyl, Cy and [Nb(h5-C5H4SiMe3)2(P(I)Ph2)(CNXylyl)]I3
Organometallics 2006, 25, 3698-3705

129.-Synthesis and reactivity of asymmetrically substituted ansa-bridged zirconocene complexes. X-ray crystal structures of [Zr{R(H)C(h5-C5Me4)(h5-C5H4)}Cl2] (R = Bun, But) and [Zr{Bun(H)C(h5-C5Me4)(h5-C5H4)}(CH2Ph)2]
J. Organomet. Chem. 691, 2006, 2924-2932

128.-Antonio Antiñolo, Santiago García-Yuste, Maria Isabel Lopez-Solera, Antonio Otero, Juan C. Pérez-Flores, Rebeca Reguillo-Carmona, Elena Villaseñor
“Activation of a CNXylyl ancillary ligand in the reaction of electron-deficient alkynes with a phosphido niobocene complex. X-ray Crystal Structure of [Nb(h5-C5H4SiMe3)2(h1-C-k1-P-C(=N(Xylyl))C(CO2Me)C(H)PPh2)]”
Dalton Trans. 2006, 1495-1496

127.- Antonio Antiñolo, Iván Dorado, Mariano Fajardo, Andrés Garcés, Marek M. Kubicki , Carmen López-Mardomingo, Antonio Otero, Sanjiv Prashar
Synthesis and reactivity of new mono and dinuclear niobium and tantalum imido complexes: X-ray crystal structure of [Ta(η5-C5H4SiMe3)Cl2{=NC6Me4-4-(N(SiMe3)2)}]
J.Organomet. Chem. 691 (2006) 1361–1368

126.-Antonio Antiñolo, Santiago García-Yuste, Antonio Otero, Juan C. Pérez-Flores, Rebeca Reguillo-Carmona, Ana M. Rodríguez, Elena Villaseñor
“Reactivity of a Phosphido-Niobocene Derivative Toward CS2 and Alkyl Halides to Give Phosphinodithioformato- and Phosphino-Niobocene Complexes; X-ray Crystal Structures of [Nb(h5-C5H4SiMe3)2(k1-S-SC(S)(PPh2))(CO)] and [Nb(h5-C5H4SiMe3)2(P(I)Ph2)(CO)]I3”
Organometallics 2006, 25, 1310-1316

125.- Carlos Alonso-Moreno, Antonio Antiñolo, Fernando Carrillo-Hermosilla, Antonio Otero, Ana M. Rodríguez, José Sancho, Victoria Volkis and Moris Eisen
Synthesis, characterization and catalytic properties of ansa-zirconocenes [Zr{1-Me2Si(3-h5-C9H5R)2}Cl2] (R = Me, nPr, nBu and Bz)
Eur. J. Inorg. Chem. 2006, 972-979

124.- Pedro J. Aragón, Fernando Carrillo-Hermosilla, Elena Villaseñor, Antonio Otero,
Antonio Antiñolo and Ana M. Rodríguez
“Synthesis, Structure and Reactivity in Styrene Polymerization by Heterocyclic
Alkoxy- and Thiolatotitanium(IV) Complexes”
Eur. J. Inorg. Chem. 2006, 965-971

123.-Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, Luis Sánchez-Barba, Margarita Sánchez-Molina, Sonia Franco, Isabel López-Solera, and Ana M. Rodríguez
“A Simple and Efficient Synthetic Route to Enantiopure Scorpionate Ligands”
Eur. J. Inorg. Chem. 2006, 707-710.

122.- S. Prashar, A. Antiñolo, A. Otero
“Insights into Group 4 and 5 ansa-Bis(cyclopentadienyl) Complexes with a single-atom bridge “
Coord. Chem. Rev., 250 (2006) 133–154

121.- Mayreli Ortiz, Ariadna Penabad, Alicia Díaz, Roberto Cao, Antonio Otero,
Antonio Antiñolo, and Agustín Lara.
“Ruthenium Complexes of the Scorpionate Ligand Bis (3,5-dimethylpyrazol-1-yl)-dithio acetate and the Effect of Nitric Oxide Coordination”
Eur. J. Inorg. Chem. 2005, 3135-3140.

120.-Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, Luis Sánchez-Barba, Emilia Martínez-Caballero, Ana M. Rodríguez, and Isabel López-Solera
“First Complexes of Scandium and Yttrium with NNO and NNS Heteroscorpionate Ligands”
Inorg. Chem. 44(2005)5336

119.- Carlos Alonso-Moreno,Antonio Antiñolo, Fernando Carrillo-Hermosilla, Pedro Carrión, Isabel López-Solera, Antonio Otero, Sanjiv Prashar, and José Sancho
“Novel Indenylzirconium Complexes as Supported Catalysts in the Polymerization of Ethylene”
Eur. J. Inorg. Chem. 2005, 2924-2934

118.- Santiago Gómez-Ruiz, Sanjiv Prashar, Mariano Fajardo, Antonio Antiñolo, Antonio Otero, Miguel A. Maestro, Victoria Volkis, Moris S. Eisen d, César J. Pastor.
‘Synthesis, hydrosilylation reactivity and catalytic properties of group 4 ansa-metallocene complexes’
Polyhedron 24 (2005) 1298–1313

117.- Antonio Antiñolo, Santiago García-Yuste, Isabel López-Solera, Antonio Otero, Juan Carlos Perez-Flores, Isabel del Hierro, Laurent Salvi, Helene Cattey, Yves Mugnier
“New reactivity of Cp’2NbH3; Cp’ C5H4SiMe3. Synthesis, electrosynthesis and reactivity of new carboxylato niobocene complexes”
J.Organomet. Chem. 690 (2005) 3134–3141

116.- A. Otero, J. Fernández-Baeza, A. Antiñolo, J. Tejeda, A. Lara-Sánchez, L. Sánchez-Barba y A. M. Rodríguez.
“Titanium and niobium imido complexes stabilized by heteroscorpionate ligands.”
J.Chem. Soc. Dalton Trans. 2004, 3963-3969

115.- Laurent Salvi, Alain Vallat, Helene Cattey, Yves Mugnier, Antonio Antinolo,
Antonio Otero, Santiago Garcıa-Yuste
“Electron-transfer-catalyzed ligand substitution of carboxylato niobocene complex induced by electrochemical oxidation”
J.Organomet. Chem. 689 (2004) 3473–3480

114.- Antonio Antiñolo, Rafael Fernández-Galan, Antonio Otero, Sanjiv Prashar, Ivan Rivilla, Ana M. Rodríguez, Miguel Maestro
“New Synthon in the Desing of ansa-Cyclopentadienyl Ligands with Variable Substitution at the Bridging Atom. New ansa-Zirconocene Complexes”
Organometallics 2004,23, 5108-5111.

113.- Antonio Antiñolo, Mariano Fajardo, Santiago Gómez-Ruiz, Isabel López-Solera, Antonio Otero, Sanjiv Prashar
“Hydrosilylation in the Design and Functionalization of ansa-Metallocene Complexes”
Organometallics 2004,23,4062-4069.
112.-Alonso, Carlos; Antiñolo, Antonio; Carrillo-Hermosilla, Fernando; Carrión, Pedro; Otero, Antonio; Sancho, Jose; Villaseñor, Elena.
“Modified silicas as supports for single-site zirconocene catalysts.”
Journal of Molecular Catalysis A: Chemical (2004), 220(2), 285-295.

111.- Mayreli Ortiz, Alicia Díaz, Roberto Cao, Reynier Suardíaz, Antonio Otero,Antonio Antiñolo, and Juan Fernández-Baeza
“Ruthenium Nitrosyl Complexes of Bis(3,5-dimethylpyrazol-1-yl)methane Oxyanions”
Eur. J. Inorg. Chem. 2004,3353-3357

110.-A. Otero, J. Fernández-Baeza, A. Antiñolo, J. Tejeda and A. Lara-Sánchez “Heteroscorpionate ligands based on bis(pyrazol-1-yl)methane: design and coordination chemistry”
J.Chem. Soc. Dalton Trans. 2004, 1499-1510

109.- Iván Dorado, Andrés Garcés, Isabel López-Solera, Marek Kubicki, Carmen López-Mardomingo, Mariano Fajardo, Antonio Antiñolo, Antonio Otero
“Isocyanide insertion reactivity of dinuclear niobium and tantalum imido complexes. X-ray crystal structure of [{Nb(h5-C5H4SiMe3)(CH2Ph)2}2(m-1,4-NC6H4N)]’
J.Organomet. Chem. 689(2004)1304

108.-A. Otero, J. Fernández-Baeza, A. Antiñolo, J. Tejeda, A. Lara-Sánchez, M. Fernández-López, and I. López-Solera
“New Complexes of Zirconium(IV) and Hafnium(IV) with Heteroscorpionate Ligands and the Hydrolysis of Such Complexes To Give a Zirconium Cluster”
Inorg. Chem. 43(2004)1350

107.-Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, Luis Sánchez-Barba, Ana M. Rodríguez, and Miguel A. Maestro
“An Unprecedented Hybrid Scorpionate/Cyclopentadienyl Ligand”
J.Am.Chem.Soc. 126(2004)1330

106.- Iván Dorado, Andrés Garcés, Isabel López-Solera, Marek Kubicki, Carmen López-Mardomingo, Mariano Fajardo, Antonio Antiñolo, Antonio Otero
Synthesis, Structural Characterisation and Reactivity of New Dinuclear Monocyclopentadienyl Imidoniobium and -tantalum Complexes. Crystal and molecular structures of [{Nb(h5-C5H4SiMe3)Cl2}2(m-1,4-NC6H4N)], [{Ta(h5-C5Me5)Cl2}2(m-1,4-NC6H4N)], [{Nb(h5-C5H4SiMe3)(CH2C6H5)2}2(m-1,4-NC6H4N)] and [{Ta(h5-C5Me5)(CH2SiMe3)2}2(m-1,4-NC6H4N)]
Eur. J. Inorg. Chem. 2004,1299

105.-Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda,
Agustín Lara-Sánchez, Luis Sánchez-Barba, and Ana M. Rodríguez
“New Complexes of Niobium(V) and Tantalum(V) with Monoanionic NNO Heteroscorpionate Ligands”
Eur. J. Inorg. Chem. 2004, 260

104.-A. Antiñolo, M. Fajardo, S. Gómez-Ruiz, I. López-Solera, A. Otero, S. Prashar, A.M. Rodríguez ”Group 4 Metallocene Complexes Incorporating Vinyl or Allyl Substituted ansa Ligands. X-ray Crystal Structures of [Zr{Me(CH2=CH)Si(h5-C5Me4)2}Cl2], [Zr{Me(CH2=CHCH2)Si(h5-C5H4)2}Cl2] and [Zr{Me(CH2=CHCH2)Si(h5-C5Me4)(h5-C5H4)}Cl2]”
J.Organomet. Chem. 683 (2003) 11

103.- Antonio Otero, Fernando Carrillo-Hermosilla, Pilar Terreros, Teresa Exposito, Sergio Rojas, Juan Fernandez-Baeza, Antonio Antiñolo, and Isabel Lopez-Solera
“Synthesis, Structure and Reactivity of New Late Transition Metal Complexes Bearing Diphosphane Ligands Derived from Bis(pyrazol-1-yl)methane”
Eur. J. Inorg. Chem. 2003, 3233

102.-A. Antiñolo, R. Fernández-Galán, B. Gallego, A. Otero, S. Prashar, A.M. Rodríguez
Synthesis and Reactivity of Alkyl Zirconium Complexes Incorporating Asymmetrically Substituted ansa-Ligands. X-ray Crystal Structure of [Me2Si(h5-C5Me4)(h5-C5H3Me)]Zr(CH2Ph)Cl
Eur. J. Inorg. Chem. 2003, 2626

101.-I. del Hierro, R. Fernández-Galán, S. Prashar, A. Antiñolo, M. Fajardo, A.M. Rodríguez, A. Otero
The Reactivity Allyl and Olefin-Hydride Niobocene Derivatives Towards Isocyanides. X-ray Crystal Structure of [Nb(h5-C5H4SiMe3)2(h3-CHRCHCHR)] (R = SiMe2tBu)
Eur. J. Inorg. Chem. 2003, 2438

100.-A. Otero, J. Fernández-Baeza, A. Antiñolo, J. Tejeda, A. Lara-Sánchez, L. Sánchez-Barba, M. T. Expósito, A. M. Rodríguez
“Niobium complexes containing a new chiral heteroscorpionate ligand and the reactivity of such a complex with O2 to give the first gem-diolate niobium complex”
J.Chem. Soc. Dalton Trans. 2003, 1614

99.- Antonio Antiñolo, Iván Dorado, Mariano Fajardo, Andrés Garcés, Marek M. Kubicki, Carmen López-Mardomingo and Antonio Otero
“Synthesis and structural characterisation of new organo-diimido tantalum and niobium complexes”
J.Chem. Soc. Dalton Trans. 2003, 910

98.- Antonio Antiñolo, Cristina García-Yebra, Mariano Fajardo, Isabel del Hierro, Carmen López-Mardomingo, Isabel López-Solera, Antonio Otero, Yolanda Pérez and Sanjiv Prashar
“Síntesis and Reactivity of Alkynyl niobiocene complexes”
J.Organomet. Chem. 670(2003)123

97.- Antonio Antiñolo, Mariano Fajardo, Antonio Otero and Sanjiv Prashar.
“Sandwich and Half Sandwich Niobium Imido Complexes”
Eur. J. Inorg. Chem. 2003, 17

96.- Otero, A; Fernández-Baeza, J; Antiñolo, A; Carrillo-Hermosilla, F; Tejeda, J; Lara-Sánchez, A; Sánchez-Barba, L; Fernández-López, M; Rodríguez, AM; López-Solera, I
“Preparation of new monoanionic “scorpionate” ligands: Synthesis and structural characterization of titanium(IV) complexes bearing this class of ligand”
Inorganic Chemistry, 41 (2002)5193-5202

95.- Antonio Antiñolo, Teresa Expósito, Isabel del Hierro, Dominique Lucas, Yves Mugnier, Irache Orive, Antonio otero, Sanjiv Prashar
Synthesis and Electrochemistry of Niobiun Complexes Incorporating Asymmetrically Subtituted ansa Ligands.
J.Organomet. Chem. 655(2002)63-69

94.-Antonio Antiñolo, Isabel López-Solera, Antonio Otero, Sanjiv prashar, Ana M. Rodríguez and Elena Villaseñor.
Reactivity of Zirconium Complexes Incorporating Asymmetrically Substituted ansa Ligands and their use as Catalyst in Olefin Polymerization. X-Ray Crystal Structure of [Me2Si(h 5 -C5Me4)(h 5 -C5H3R)]ZrCl2 (R) Et, iPr)”
Organometallics 2002,21,2460-2467

93.-Antonio Antiñolo, Rafael Férnandez-Galan, Irache Orive, Antonio Otero, Sanjiv Prashar
“New Group 4 Metallocene and Niobiocene Complexes Containing Phosphine Functionalized ansa-ligands”
Eur. J. inorg. Chem. 2002 2470-2476

92.-Carlos Alonso-Moreno, Antonio Antiñolo, Isabel López-Solera, Antonio Otero, Sanjiv Prashar, Ana M. Rodríguez, Elena Villaseñor.
“Niobium, Titanium and Hafnium Complexes Incorporating Bridges ansa ligand. X-Ray Crystal Structures of [Zr{Me2Ge(h 5-C5Me4)2}Cl2 and [M{Me2Si(h 5 -C5Me4)(h 5 -C5H4)} Cl2] (M= Zr, Hf)”
J.Organomet. Chem. 656(2002)129-138

91.- Jorge Moniz Santos, Maria Rosario Ribeiro, Manuel Farinha Portela, Henri Cramail, Alain Deffieux, Antonio Antiñolo, Antonio Otero, Sanjiv Prashar
“[(h5-C5Me4)SiMe2(NtertBu)]TiCl2 as Pre-Catalyst for the Copolymerisation of Ethylene with 5,7-Dimethylocta-1,6-diene and with 3,7-Dimethylocta-1,6-diene”
Macromol. Chem. Phys. 2002, 203, 139-145

90.- Antonio Antiñolo, Isabel López-Solera, Antonio Otero y Sanjiv Prashar
“The synthesis of alkyl niobocene imido complexes and the X-ray crystal structure of [Nb(O)Cp2Me](Cp=5-C5H5)”
Journal of Organometallic Chemistry, 631, 2001, 151

89.- Otero A. Fernández-Baeza J. Antiñolo A. Carrillo-Hermosilla F. Tejeda J. Lara-Sánchez A. Lopez-Solera I.
“Synthesis and spectroscopic characterization of alpha-keto ylide-containing Group 4 metal complexes. The X-ray molecular structure of [Cp*ZrCl3(2-TCMP)], Cp* = h5-C5Me5, 2-TCMP = [{2-thiazolylcarbonyl}methylene]triphenylphosphorane”
J. Organomet. Chem. 629, 2001, 68-76

Seleccionados 1984-2000
I. DORADO, A. GARCÉS, C. LÓPEZ-MARDOMINGO, M. FAJARDO, A. RODRÍGUEZ, A. ANTIÑOLO, A. OTERO
Synthesis and structural characterización of new organo-diimido and organo-imido niobium and titanium complexes
J. Chem. Soc., Dalton Trans., 2375-2382, (2000).

 

C. GARCÍA-YEBRA, C. LÓPEZ-MARDOMINGO, M. FAJARDO, A. ANTIÑOLO, A. OTERO, A. RODRÍGUEZ, A. VALLAT, D. LUCAS, Y MUGNIER, J.J. CARBÓ, A. LLEDÓS, C. BO
Facile synthesis of alkynyl- and vinylidene-niobocene complexes. Unexpected h1-vinylidene-h2-alkyne isomerization
Organometallics, 19: 1749-1765, (2000).

 

A. ANTIÑOLO, I. DEL HIERRO, I. LÓPEZ-SOLERA, S. GARCÍA-YUSTE, A. OTERO, M. FAJARDO, A. RODRÍGUEZ
Synthesis and reactivity of new oxo alkyl or oxo acyl niobocene complexes and crystal structure of Cp’2Nb(=O(OC(O)CF3)(Cp’=h5-C5H4SiMe3)
Journal of Organometallic Chemistry, 598: 167-173, (2000).

 

C. GARCÍA-YEBRA, F. CARRERO, C. LÓPEZ-MARDOMINGO, M. FAJARDO, A. RODRÍGUEZ, A. ANTIÑOLO, A. OTERO, D. LUCAS, I. MUGNIER
New niobocene alkyne complexes: synthesis and characterization of neutral and cationic niobium complexes with functionalized alkynes. X-ray crystal structure of [Nb(? 5- C5H4SiMe3)2(Cl)(? 2(C,C)-R1C? CR2)](R1 = C? CPh, R2 = Ph (2b); R1 = CH2CH=C(CH3)2, R2 = Ph (3b)
Organometallics, 18: 1287-1298, (1999)

 

A. ANTIÑOLO, M. FAJARDO, C. HUERTA, A. OTERO, S. PRASHAR, A. M. RODRÍGUEZ
Sandwich and half-sandwich niobium imido complexes: X-ray crystal structure of [Nb(=NAr)Cp’2Cl] (Cp’ = h5-C5H4SiMe3, Ar = C6H4OMe-4)
Journal of Organometallic Chemistry, 585: 154-161, (1999)

 

C. GARCÍA-YEBRA, A. ANTIÑOLO, F. CARRILLO-HERMOSILLA, M. FAJARDO, J. FERNÁNDEZ-BAEZA, S. GARCÍA-YUSTA, A. OTERO
Advances in the chemistry of bis-cyclopentadienyl hydride derivatives of niobium and tantalum.
Coord. Chem. Rev., 193 (195):43-72, (1999)

 

Z. M. TEHRANI, D. LUCAS, Y. MUGNIER, A. ANTIÑOLO, A. OTERO, M. FAJARDO, A. GARCÉS, C. LÓPEZ-MARDOMINGO
Electrocatalytic process in the reduction of {Nb[h5-C5H4(SiMe3)]2(Cl)(NHPh)}BF4
Journal of Organometallic Chemistry, 548:309-313, (1997)

 

A. ANTIÑOLO, F. CARRILLO-HERMOSILLA, A. OTERO, M. FAJARDO, A. GARCÉS, P. GÓMEZ-SAL, C. LÓPEZ-MARDOMINGO, A. MARTÍN, C. MIRANDA
Synthesis and structural characterization of isocyanate, amido and imido niobocene derivatives:crystal structures of [Nb(h5-C5H4SiMe3)2Cl(k2N,C-OCNPh] and [{Nb(h5-C5H4SiMe3)2Cl}2-(m-1,3-N2C6H4)
J. Chem. Soc., Dalton Trans., 59-65, (1998)

 

A. ANTIÑOLO, F. CARRILLO-HERMOSILLA, A. CASTEL, M. FAJARDO, J. FERNÁNDEZ-BAEZA, M. LANFRANCHI, A. OTERO, M. A. PELLINGHELLI, G. RIMA, J. SATGÉ, E. VILLASEÑOR
Synthesis and characterization of the first niobocene germyl complexes and reactivity of triphenylsilyl-, triphenylgermyl-, and triphenylstannylniobocene derivatives. X-ray molecular structures of d0 Nb(h5-C5H4SiMe3)2(H)2(EPh3) (E = Ge, Sn)
Organometallics, 17:1523-1529, (1998)

 

A. Antiñolo; F. Carrillo-Hermosilla; S. García-Yuste; M. Freitas; A. Otero; S. Prashar; E. Villaseñor; M. Fajardo
Insertion reactions of heterocumulenes into the niobium-hydride bond of isocyanide and carbonyl niobocene complexesInorg. Chim. Acta 1997, 259, 101-105.

 

A. Antiñolo; F. Carrillo-Hermosilla; M. Fajardo; S. García-Yuste; A. Otero; S. Camanyes; F. Maseras; M. Moreno; A. Lledós; J. M. Lluch Synthesis and Spectroscopic Properties of Dihydrogen Isocyanide Niobocene [Nb(h5-C5H4SiMe3)2(h2-H2)(CNR)]+ Complexes. Experimental and Theroretical Study of the Blocked Rotation of a Coordinated Dihydrogen
.J. Am. Chem. Soc. 1997, 119, 6107-6114

 

A. Antiñolo; A. Otero; M. Fajardo; R. Gil-Sanz; M. J. Herranz; C. López-Mardomingo; A. Martín; P. Gómez-Sal
Synthesis, structure, and chemistry of hydrido and alkyl niobocene Ketene and Ketenimine derivatives. X-ray crystal structure of [Nb(h5-C5H4SiMe3)2(CH3)(h2-(C,O)O=C=CPh2)] J. Organomet. Chem. 1997, 533, 87-96.
A. Antiñolo; F. Carrillo-Hermosilla; I. D. Hierro; A. Otero; M. Fajardo; Y. Mugnier Synthesis and Characterization of New Alkyl-Carbon Dioxide Compounds and the First Neutral Acyl-Carbonyl Niobocene Complexes Organometallics 1997, 16, 4161-4166.

 

A. Antiñolo; A. Otero; M. Fajardo; C. García-Yebra; C. López-Mardomingo; A. Martín; P. Gómez-Sal Niobocene Alkyne Complexes: Synthesis and Characterization of Neutral and Cationic d2 Metal Alkyne Derivatives. X-ray Crystal Structure of [Nb(h5-C5H4SiMe3)2(h2(C,C)-HC=CPh)(CH2Ph)]Organometallics 1997, 16, 2601-2611.

 

A. Antiñolo; F. Carrillo-Hermosilla; B. Chaudret; M. Fajardo; J. Fernández-Baeza; M. Lanfranchi; H. H. Limbach; M. Maurer; A. Otero; M. A. Pellinghelli Exchange Coupling in Niobocene Trihydrides, Nb(C5H3RR’)2H3, and Their Adducts with Copper Triad Cations, [{Nb(C5H3RR’)2H3}2M]+ (R=R’=H; R=H,R’=SiMe3, R=R’=SiMe3; M=Cu, Ag, Au)Inorg. Chem. 1996, 35, 7873-7881
S. E. Krami; Y. Mourad; D. Lucas; Y. Mugnier; A. Antiñolo; M. Fajardo; S. García-Yuste; A. Otero Electrochemical synthesis and reactivity of carbonato-niobocene complexes J. Organomet. Chem. 1996, 525, 125-131.

 

D. Lucas; Z. Modarres-Tehrani; Y. Mugnier; A. Antiñolo; I. Del Hierro; A. Otero; M. Fajardo New nitrile niobocene complexes; electrochemical studies on their h1/h2 nitrile isomerization processes New J. Chem. 1996, 20, 385-391.

 

A. Antiñolo; F. Carrillo-Hermosilla; M. Fajardo; S. García-Yuste; M. Lanfranchi; A. Otero; M. A. Pellinghelli; S. Prashar; E. Villaseñor Studies on the Insertion Reactions of Activated Alkynes into Nb-H Bonds in Hydride-Niobocene Complexes. X-ray Crystal Structures of Nb(h5-C5H4SiMe3)2(H)[h2-RO2C(H)=C(H)CO2R](R=Me or tBu) Organometallics 1996, 15, 5507-5513.

 

A. Antiñolo; I. Del Hierro; M. Fajardo; S. García Yuste; A. Otero; O. Blacque; M. M. Kubicki; J. Amaudrut Chemistry of h2-CS2 Niobocene Complexes: Synthesis and Characterization of New 1,3-dithiol-2-ylidene Complexes via Reactions with Activated Alkynes Organometallics 1996, 15, 1966-1971.